Researcher Profile and Settings

Researcher

• Name

  KANNO Kenichiro

Affiliation

• Division of Materials and Environment（Department of Applied Chemistry）, Associate Professor

Profile and Settings

• Name

  Kanno, Ken-ichiro

Affiliation

• Gunma University, Associate Professor
• Gunma University, Associate Professor

Affiliation

• Affiliation

  Graduate School of Science and Technology

Education

• 2001
• 1996, Tohoku University, Faculty of Science, Department of Chemistry

Association Memberships

• The Chemical Society of Japan
• The Society of Silicon Chemistry, Japan

Research Experience

• Apr. 2001, Mar. 2003, Hokkaido University, Catalysis Research Center
• Apr. 2003, Mar. 2007, Hokkaido University, Catalysis Research Center
• Apr. 2007, Mar. 2010, Hokkaido University, Catalysis Research Center
• Apr. 2010
• Gunma University, Associate Professor, Associate prof lecturer lv
• Gunma University
• Hokkaido University Catalysis Research Center, Research Associate, Researcher postdoc lv

Research Activities

Research Areas

• Manufacturing technology (mechanical, electrical/electronic, chemical engineering), Electronic devices and equipment
• Nanotechnology/Materials, Functional solid-state chemistry
• Nanotechnology/Materials, Structural/physical organic chemistry
• Life sciences, Bioorganic chemistry

Research Interests

• organic chemistry
• organometallic chemistry
• organoelemental chemistry
• organosilicon chemistry
• organosilicon chemistrytransition metal complex

Research Themes

• Development of Synthetic Methods of Organosilicon Compounds by Transition-Metal Complexes, Personal, 2010, Organic Chemistry, Synthetic Chemistry, Grants and Funding

Published Papers

• Selective linear triene formation from different alkynes using Zr/Cu system, Ken-ichiro Kanno; Ed Igarashi; Lishan Zhou; Kiyohiko Nakajima; Tamotsu Takahashi, Apr. 2008, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130, 17, 5624, +, Scientific journal

  DOI
• Once Cleaved C-C Bond Was Reformed: Reversible C-C Bond Cleavage of Dihydroindenyltitanium Complexes, Tamotsu Takahashi; Zhiyi Song; Yi-Fang Hsieh; Kiyohiko Nakajima; Ken-ichiro Kanno, Nov. 2008, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130, 46, 15236, +, Scientific journal

  DOI
• Regioselective zirconophosphination of 1-alkenes: A versatile route for the synthesis of beta-functionalized alkyldiphenylphosphine oxides in the presence of CuCl, Chanjuan Xi; Xiaoyu Yan; Chunbo Lai; Ken-ichiro Kanno; Tamotsu Takahashi, Aug. 2008, ORGANOMETALLICS, 27, 15, 3834, 3839, Scientific journal

  DOI
• Substituent effects in the preparation of naphthacenes by the coupling reaction of diyne-derived zirconacyclopentadienes with tetraiodobenzene, Tomomi Seri; Hongmei Qu; Lishan Zhou; Ken-ichiro Kanno; Tamotsu Takahashi, 2008, CHEMISTRY-AN ASIAN JOURNAL, 3, 2, 388, 392, Scientific journal

  DOI
• HETEROCYCLE FORMATION FROM ZIRCONACYCLES, Lishan Zhou; Masamichi Yamanaka; Ken-ichiro Kanno; Tamotsu Takahashi, Nov. 2008, HETEROCYCLES, 76, 2, 923, 947, Scientific journal

  DOI
• Double Homologation Method for Substituted Soluble Pentacenes and Dimerization Behaviours of Pentacenes, Shi Li; Zhiping Li; Kiyohiko Nakajima; Ken-ichiro Kanno; Tamotsu Takahashi, 2009, CHEMISTRY-AN ASIAN JOURNAL, 4, 2, 294, 301, Scientific journal

  DOI
• Zirconium-Mediated Selective Synthesis of 1,2,4,5-Tetrasubstituted Benzenes from Two Silyl-Substituted Alkynes and One Internal Alkyne, Shi Li; Hongmei Qu; Lishan Zhou; Ken-ichiro Kanno; Qiaoxia Guo; Baojian Shen; Tamotsu Takahashi, Aug. 2009, ORGANIC LETTERS, 11, 15, 3318, 3321, Scientific journal

  DOI
• Synthesis of acenes via coupling of 1,4-dilithiobutadienes with diiodoarenes in the presence of CuCl, Lishan Zhou; Kiyohiko Nakajima; Ken-ichiro Kanno; Tamotsu Takahashi, Jun. 2009, TETRAHEDRON LETTERS, 50, 23, 2722, 2726, Scientific journal

  DOI
• Coupling of the R-Cp or Indenyl Ligand with the Diene Moiety of Bis(substituted cyclopentadienyl)- or Bis(indenyl)zirconacyclopentadienes, Shenyong Ren; Eri Igarashi; Kiyohiko Nakajima; Ken-ichiro Kanno; Tamotsu Takahashi, Jun. 2009, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 131, 22, 7492, +, Scientific journal

  DOI
• Zirconium-Mediated Coupling Reaction for Synthesis of Substituted Thiophene-Fused Acenes, Yang Ni; Kiyohiko Nakajima; Ken-ichiro Kanno; Tamotsu Takahashi, Aug. 2009, ORGANIC LETTERS, 11, 16, 3702, 3705, Scientific journal

  DOI
• Selective catalytic monoreduction of dichlorooligosilanes with Grignard reagents, Ken-ichiro Kanno; Yuka Niwayama; Soichiro Kyushin, Dec. 2013, TETRAHEDRON LETTERS, 54, 50, 6940, 6943, Scientific journal

  DOI
• Synthesis of 1,2,3,4,8,9,10,11-Octasubstituted Pentacenequinone Derivatives and their Conversion into Substituted Pentacenes, Shi Li; Lishan Zhou; Kiyohiko Nakajima; Ken-ichiro Kanno; Tamotsu Takahashi, 2010, CHEMISTRY-AN ASIAN JOURNAL, 5, 7, 1620, 1626, Scientific journal

  DOI
• RECENT DEVELOPMENT FOR FORMATION OF AROMATIC COMPOUNDS VIA METALLACYCLOPENTADIENES AS METAL-CONTAINING HETEROCYCLES, Lishan Zhou; Shi Li; Ken-ichiro Kanno; Tamotsu Takahashi, Mar. 2010, HETEROCYCLES, 80, 2, 725, 738, Scientific journal

  DOI
• Selective Protonation/Iodination of Unsymmetrical Zirconacyclopentadienes, Eri Igarashi; Shenyong Ren; Ken-ichiro Kanno; Tamotsu Takahashi, Apr. 2010, CHEMISTRY LETTERS, 39, 4, 350, 351, Scientific journal

  DOI
• Early transition metal-catalyzed cross-coupling reaction of aryl fluorides with a phenethyl grignard reagent accompanied by rearrangement of the phenethyl group, HQ Guo; FZ Kong; K Kanno; JJ He; K Nakajima; T Takahashi, Apr. 2006, ORGANOMETALLICS, 25, 8, 2045, 2048, Scientific journal

  DOI
• Homologation method for preparation of substituted pentacenes and naphthacenes, Tamotsu Takahashi; Shi Li; Wenying Huang; Fanzhi Kong; Kiyohiko Nakajima; Baojian Shen; Takahiro Ohe; Ken-Ichiro Kanno, Oct. 2006, JOURNAL OF ORGANIC CHEMISTRY, 71, 21, 7967, 7977, Scientific journal

  DOI
• Isolation of 6,13-dipropylpentacene and its tautomerization, Tamotsu Takahashi; Ken Kashima; Shi Li; Kiyohiko Nakajima; Ken-ichiro Kanno, Dec. 2007, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129, 51, 15752, +, Scientific journal

  DOI
• Intermolecular coupling of alkynes, isocyanates, and acyl chlorides: an efficient method for the synthesis of 5-hydroxypyrrol-2(5H)-ones, Ken-ichiro Kanno; Shenyong Ren; Yanzhong Li; Kiyohiko Nakajima; Tamotsu Takahashi, Dec. 2007, TETRAHEDRON LETTERS, 48, 52, 9199, 9202, Scientific journal

  DOI
• Cu(I)-mediated cycloaddition reaction of zirconacyclopentadienes with fumaronitrile and application for synthesis of monocyano-substituted pentacenes, Tamotsu Takahashi; Yanzhong Li; Jinghan Hu; Fanzhi Kong; Kiyohiko Nakajima; Lishan Zhou; Ken-ichiro Kanno, Sep. 2007, TETRAHEDRON LETTERS, 48, 38, 6726, 6730, Scientific journal

  DOI
• 1-chloro-4,5,6,7-tetraalkyldihydroindene formation by reaction of bis(cyclopentadienyl)titanacyclopentadienes with titanium chloride, Tamotsu Takahashi; Zhiyi Song; Kimihiko Sato; Yuichi Kuzuba; Kiyohiko Nakajima; Ken-ichiro Kanno, Sep. 2007, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 129, 38, 11678, +, Scientific journal

  DOI
• Carrier mobility for organic semiconductors: Reduction of noise of the short part drift time in the time of flight mobility method, Ken Kashima; Hiroshi Sato; Kiyoshi Musha; Ken-Ichiro Kanno; Tamotsu Takahashi, Oct. 2007, ANALYTICAL SCIENCES, 23, 10, 1249, 1251, Scientific journal

  DOI
• Formation of linear tetramers of diarylalkynes by the Zr/Cr system, T Takahashi; YH Liu; A Iesato; S Chaki; K Nakajima; K Kanno, Aug. 2005, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 127, 34, 11928, 11929, Scientific journal

  DOI
• Chromium-mediated synthesis of polycyclic aromatic compounds from halobiaryls, K Kanno; YH Liu; A Iesato; K Nakajima; T Takahashi, Nov. 2005, ORGANIC LETTERS, 7, 24, 5453, 5456, Scientific journal

  DOI
• Direct reactions of zirconacyclopentadienes with halosilanes as a convenient synthetic method for siloles, K Kanno; M Kira, Oct. 1999, CHEMISTRY LETTERS, 10, 1127, 1128, Scientific journal

  DOI
• APPLICATION OF ZIRCONACYCLOPENTADIENES (METALLA-HETEROCYCLES) AND CROSS-COUPLING FOR THE CONVENIENT PREPARATIVE METHOD OF 6,13-DISUBSTITUTED PENTACENE, Zhiying Jia; Shi Li; Kiyohiko Nakajima; Ken-ichiro Kanno; Zhiyi Song; Tamotsu Takahashi, Dec. 2012, HETEROCYCLES, 86, 2, 1495, 1506, Scientific journal

  DOI
• One-pot synthetic routes to multiply substituted indene derivatives by hydrolysis of zirconocene-mediated intermolecular coupling reactions of aromatic ketones and alkynes, ZF Xi; RY Guo; S Mito; HL Yan; K Kanno; K Nakajima; T Takahashi, Feb. 2003, JOURNAL OF ORGANIC CHEMISTRY, 68, 4, 1252, 1257, Scientific journal

  DOI
• Novel synthetic route to octasubstituted naphthalenes from four alkynes and one olefin unit via zirconacyclopentadienes and 1,2-diiodo-3,4,5,6-tetraalkylbenzene, Zhou, X; ZP Li; H Wang; M Kitamura; K Kanno; K Nakajima; T Takahashi, Jun. 2004, JOURNAL OF ORGANIC CHEMISTRY, 69, 13, 4559, 4562, Scientific journal

  DOI
• Iron-catalyzed dechlorination of aryl chlorides, HQ Guo; K Kanno; T Takahashi, Oct. 2004, CHEMISTRY LETTERS, 33, 10, 1356, 1357, Scientific journal

  DOI
• Pd-catalyzed reactions of o-diiodoarenes with alkynes for aromatic ring extension, WY Huang; Zhou, X; K Kanno; T Takahashi, Jul. 2004, ORGANIC LETTERS, 6, 14, 2429, 2431, Scientific journal

  DOI
• Synthesis and structure of a series of oligo[1,1-(2,3,4,5,-tetramethylsilole)]s, K Kanno; M Ichinohe; C Kabuto; M Kira, 1998, CHEMISTRY LETTERS, 1, 99, 100, Scientific journal

  DOI
• Formation of Seven-Membered Carbocycles via 7-endo Mode Cyclization of Lithioheptatrienes, Ken-ichiro Kanno; Efi Igarashi; Yuki Mizukami; Kiyohiko Nakajima; Zhiyi Song; Tamotsu Takahashi, Dec. 2016, ORGANIC LETTERS, 18, 24, 6217, 6219, Scientific journal

  DOI
• Separation of Five Linearly Aligned Carbons into Two-Carbon and Three-Carbon Groups on Titanium, Zhiyi Song; Yi-Fang Hsieh; Kiyohiko Nakajima; Ken-ichiro Kanno; Tamotsu Takahashi, Apr. 2016, ORGANOMETALLICS, 35, 8, 1092, 1097, Scientific journal

  DOI
• Coupling Reaction of a Cyclopentadienyl Ligand with a Dienyl or Alkenyl Moiety on Titanocene, Zhiyi Song; Yi-Fang Hsieh; Ken-ichiro Kanno; Kiyohiko Nakajima; Tamotsu Takahashi, Feb. 2011, ORGANOMETALLICS, 30, 4, 844, 851, Scientific journal

  DOI
• Synthesis of Co-oligomers of Thiophene Derivatives from Oligoynes via Zirconacyclopentadiene, Debabrata Payra; Zhiyi Song; Ken-ichiro Kanno; Tamotsu Takahashi, Dec. 2011, CHEMISTRY LETTERS, 40, 12, 1447, 1449, Scientific journal

  DOI
• Dehydro Side Coupling of Substituted Pentacene Derivatives, Shi Li; Zhiying Jia; Kiyohiko Nakajima; Ken-ichiro Kanno; Tamotsu Takahashi, Dec. 2011, JOURNAL OF ORGANIC CHEMISTRY, 76, 24, 9983, 9987, Scientific journal

  DOI
• Preparation of 6,13-Bis(trimethylsilyl)pentacene and Formation of Second-Ring Diels-Alder Adduct of Pentacene, Zhiying Jia; Shi Li; Kiyohiko Nakajima; Ken-ichiro Kanno; Tamotsu Takahashi, Jan. 2011, JOURNAL OF ORGANIC CHEMISTRY, 76, 1, 293, 296, Scientific journal

  DOI
• Selective Dimerization of Aryl-substituted Terminal Alkynes on Bis(indenyl)zirconocene Derivatives, Shenyong Ren; Takashi Seki; David Necas; Hiroyuki Shimizu; Kiyohiko Nakajima; Ken-ichiro Kanno; Zhiying Song; Tamotsu Takahashi, Dec. 2011, CHEMISTRY LETTERS, 40, 12, 1443, 1444, Scientific journal

  DOI
• Recent Development for Enantioselective Synthesis of Aromatic Compounds from Alkynes via Metallacyclopentadienes, Shi Li; Lishan Zhou; Ken-Ichiro Kanno; Tamotsu Takahashi, May 2011, JOURNAL OF HETEROCYCLIC CHEMISTRY, 48, 3, 517, 528, Scientific journal

  DOI
• Ruthenium-catalyzed alkoxylation of a hydrodisilane without Si-Si bond cleavage, Ken-ichiro Kanno; Yumi Aikawa; Soichiro Kyushin, Jan. 2017, TETRAHEDRON LETTERS, 58, 1, 9, 12, Scientific journal

  DOI
• Synthesis and electronic spectra of 2,5-bis-(2-arylethenyl)siloles, K. Kanno; M. Kira, Nov. 2001, Chemistry of Heterocyclic Compounds, 37, 11, 1388, 1393, Scientific journal

  DOI
• Synthesis, structures, and reactivity of 9,9-dialkoxy-9-silafluorenes, Ken-ichiro Kanno; Satoshi Hirose; Soichiro Kyushin, Dec. 2018, HETEROATOM CHEMISTRY, 29, 5-6, e21478(1), e21478(8), Scientific journal

  DOI
• Stepwise Introduction of Different Substituents to -Chloro--hydrooligosilanes: Convenient Synthesis of Unsymmetrically Substituted Oligosilanes, Ken-ichiro Kanno; Yumi Aikawa; Yuka Niwayama; Misaki Ino; Kento Kawamura; Soichiro Kyushin, Sep. 2018, INORGANICS, 6, 3, 99(1), 99(14), Scientific journal

  DOI
• Second-Ring Diels-Alder Adducts of Substituted Pentacenes, Zhiying Jia; Kiyohiko Nakajima; Ken-ichiro Kanno; Zhiyi Song; Tamotsu Takahashi, Apr. 2018, CHEMISTRYSELECT, 3, 16, 4298, 4302, Scientific journal

  DOI
• Synthesis of Silyl-substituted Anthracene Derivatives via Birch-type Silylation, Ken-ichiro Kanno; Yumika Maemura; Naotaka Kobayashi; Soichiro Kyushin, Feb. 2013, CHEMISTRY LETTERS, 42, 2, 112, 114, Scientific journal

  DOI
• Early transition metal catalyzed hydrosilation reaction, Bao, F; Kanno, K; Takahashi, T, 2008, Trends in Organic Chemistry, 12, 1, 17, Scientific journal
• Effect of substituents at 1,4-positions of polycyclic aromatic compounds and preparation of 2,3-difunctionalized pentacenes and naphthacenes, Shi Li; Lishan Zhou; Zhiyi Song; Fengyu Bao; Ken-Ichiro Kanno; Tamotsu Takahashi, Dec. 2007, HETEROCYCLES, 73, 1, 519, +, Scientific journal

  DOI
• Carbon-carbon bond cleavage reaction using metallocenes, Takahashi, T; Kanno, K, 2005, Topics in Organometallic Chemistry, 8, 217, 236, Scientific journal
• Ruthenium-catalyzed hydrosilylation of alkynes by using hydrooligosilanes without Si-Si bond cleavage, Ken-ichiro Kanno; Yumi Aikawa; Soichiro Kyushin, Sep. 2020, TETRAHEDRON LETTERS, 61, 36, 152274, Scientific journal

  DOI
• Ruthenium-catalyzed hydrosilylation of alkynes with preservation of the Si-Si bond of hydrooligosilanes: Regio-and stereoselective synthesis of (Z)-alkenyloligosilanes and carbonyl-functionalized alkenyldisilanes, Ken-ichiro Kanno; Seiya Noguchi; Yukie Ono; Saki Egawa; Naoki Otsuka; Masato Mita; Soichiro Kyushin, Mar. 2022, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 961, Scientific journal

  DOI
• Selective catalytic monoreduction of dichlorooligosilanes with Grignard reagents, Kanno, Ken-ichiro;Niwayama, Yuka;Kyushin, Soichiro, 2013, TETRAHEDRON LETTERS, 54, 50, 6940, 6943

  DOI
• Ruthenium-catalyzed alkoxylation of a hydrodisilane without Si-Si bond cleavage, Kanno, Ken-ichiro;Aikawa, Yumi;Kyushin, Soichiro, 2017, TETRAHEDRON LETTERS, 58, 1, 9, 12

  DOI
• Synthesis, structures, and reactivity of 9,9-dialkoxy-9-silafluorenes, Kanno, Ken-ichiro;Hirose, Satoshi;Kyushin, Soichiro, 2018, HETEROATOM CHEMISTRY, 29, 5-6

  DOI
• Ruthenium-catalyzed hydrosilylation of alkynes by using hydrooligosilanes without Si-Si bond cleavage, Kanno, Ken-ichiro;Aikawa, Yumi;Kyushin, Soichiro, 2020, TETRAHEDRON LETTERS, 61, 36

  DOI
• Synthesis of Silyl-substituted Anthracene Derivatives via Birch-type Silylation, KANNO Ken-ichiro;MAEMURA Yumika;KOBAYASHI Naotaka;KYUSHIN Soichiro, Feb. 2013, 42, 2, 112, 114
• Synthesis of Silyl-substituted Anthracene Derivatives via Birch-type Silylation, Kanno Ken-ichiro;Maemura Yumika;Kobayashi Naotaka;Kyushin Soichiro, 2013, Chemistry Letters, 42, 2, 112, 114
• Ring Inversion of an Organosilicon Belt-Shaped Cyclophane, Toma Yuki;Kanno Ken-ichiro;Kyushin Soichiro, 2011, Abstracts of Symposium on Physical Organic Chemistry, 2011, 0, 331, 331
• Synthesis of Silyl-substituted Anthracene Derivatives via Birch-type Silylation, Kanno, Ken-ichiro;Maemura, Yumika;Kobayashi, Naotaka;Kyushin, Soichiro, 2013, CHEMISTRY LETTERS, 42, 2, 112, 114

  DOI
• Ruthenium-catalyzed hydrosilylation of alkynes with preservation of the Si-Si bond of hydrooligosilanes: Regio-and stereoselective synthesis of (Z)-alkenyloligosilanes and carbonyl-functionalized alkenyldisilanes, Kanno, Ken-ichiro;Noguchi, Seiya;Ono, Yukie;Egawa, Saki;Otsuka, Naoki;Mita, Masato;Kyushin, Soichiro, 2022, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 961

  DOI
• Transition Metal-Catalyzed Selective Functionalization of Oligosilanes without Si-Si Bond Cleavage, Kanno, Ken-ichiro;Kyushin, Soichiro, 2022, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 80, 6, 574, 582

  DOI
• Quantum yield of near-infrared bioluminescence with firefly luciferin analog: AkaLumine, Ono, Ryohei;Osawa, Keita;Takahashi, Yutaka;Noguchi, Yoshifumi;Kitada, Nobuo;Saito-Moriya, Ryohei;Hirano, Takashi;Maki, Shojiro A.;Shibata, Keisei;Akiyama, Hidefumi;Kanno, Ken-ichiro;Itabashi, Hideyuki;Hiyama, Miyabi, 2023, JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 434

  DOI
• Photo-cleaving and photo-bleaching quantum yields of coumarin-caged luciferin, Kumagai, Ryo;Ono, Ryohei;Sakimoto, Shu;Suzuki, Chiharu;Kanno, Ken-ichiro;Aoyama, Hiroshi;Usukura, Junko;Kobayashi, Masataka;Akiyama, Hidefumi;Itabashi, Hideyuki;Hiyama, Miyabi, 2023, JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 434

  DOI
• Nickel-Catalyzed Cross-Coupling Reactions, Tamotsu Takahashi; Ken-Ichiro Kanno, 19 Aug. 2005, Modern Organonickel Chemistry, 41, 55, In book

  DOI
• Absorption and fluorescence properties and assignments of firefly bioluminescence substrate analog: seMpai., Masahiro Harada; Tomoya Nakano; Ryohei Ono; Tamotsu Uchiyama; Yoshifumi Noguchi; Ryohei Saito-Moriya; Nobuo Kitada; Shojiro A Maki; Takashi Hirano; Hiroshi Aoyama; Masataka Kobayashi; Hidefumi Akiyama; Ken-Ichiro Kanno; Hideyuki Itabashi; Miyabi Hiyama, 26 May 2025, Photochemistry and photobiology, Scientific journal

  DOI
• Synthesis of Bis(alkenyl)oligosilanes via Double Hydrosilylation and Their Structures and Photophysical Properties, Ken‐ichiro Kanno; Keisuke Kajima; Yudai Suzuki; Ryuya Honma; Soichiro Kyushin, 03 Dec. 2024, Asian Journal of Organic Chemistry, 14, 2, Scientific journal

  DOI
• Ruthenium‐Catalyzed Hydrosilylation of Aldehydes with Hydrooligosilanes, Ken‐ichiro Kanno; Yasuhiro Sunaga; Soichiro Kyushin, 17 Oct. 2024, Zeitschrift für anorganische und allgemeine Chemie, 650, 22, Scientific journal

  DOI
• Highly Twisted Ladder Oligosilanes Bearing Phenyl and tert‐Butyldimethylsilyl Groups, Soichiro Kyushin; Koichi Arai; Ken‐ichiro Kanno, Jul. 2024, Zeitschrift für anorganische und allgemeine Chemie, 650, 15, Scientific journal

  DOI
• Quantum yield of near-infrared bioluminescence with firefly luciferin analog: AkaLumine, Ryohei Ono; Keita Osawa; Yutaka Takahashi; Yoshifumi Noguchi; Nobuo Kitada; Ryohei Saito-Moriya; Takashi Hirano; Shojiro A. Maki; Keisei Shibata; Hidefumi Akiyama; Ken-ichiro Kanno; Hideyuki Itabashi; Miyabi Hiyama, Jan. 2023, Journal of Photochemistry and Photobiology A: Chemistry, 434, 114270, 114270, Scientific journal

  DOI
• Photo-cleaving and photo-bleaching quantum yields of coumarin-caged luciferin, Ryo Kumagai; Ryohei Ono; Shu Sakimoto; Chiharu Suzuki; Ken-ichiro Kanno; Hiroshi Aoyama; Junko Usukura; Masataka Kobayashi; Hidefumi Akiyama; Hideyuki Itabashi; Miyabi Hiyama, Jan. 2023, Journal of Photochemistry and Photobiology A: Chemistry, 434, 114230, 114230, Scientific journal

  DOI

MISC

• 次世代物質変換プロセスの開拓, 菅野研一郎; 高橋保, 2004, 55, 1, 1, 6, Introduction other
• 「有機薄膜光電変換素子」, 瀬理智弓; 菅野研一郎; 高橋保, 2007, 7, 2, 22, 27, Introduction other
• ジルコノセン錯体を用いた、アルキン、イソシアン酸エステル、酸塩化物からのヒドロキシピロロン誘導体の合成, 高橋保; 菅野研一郎, 2008, 37, 2, 5, 13, Introduction other
• Carbon-Carbon Bond Cleavage Reaction and Its Application Using Transition Metals, Tamotsu Takahashi; Ken-Ichiro Kanno, 2003, Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 61, 10, 938, 948, Book review

  DOI
• 炭素－炭素結合の切断を軸とした次世代物質変換プロセスの開発, 菅野研一郎; 高橋保, 2005, 50, 10, 802, 806, Introduction other
• 多環芳香族化合物の触媒プロセスへの展開, 菅野研一郎; 高橋保, 2005, 51, 679, 684, Introduction other

Books etc

• 実験化学講座第5版第21巻, Joint work, 2004, 59-74, Scholarly book
• 実験化学講座第5版第18巻, Joint work, 2004, 254-266, Scholarly book
• Modern Organonickel Chemistry, Joint work, Tamotsu Takahashi; Ken‐ichiro Kanno, Chapter 2, Nickel‐Catalyzed Cross‐Coupling Reactions, Wiley, 2005, 41-55, Scholarly book
• Acid Catalysis in Modern Organic Synthesis, Joint work, Kanno, Ken-ichiro; Takahashi, Tamotsu, Zr(IV) and Hf(IV) Lewis acids, Wiley, 2008, 2, 825-858, Scholarly book

Presentations

• Synthesis, Structures, and Properties of a Series of Bis(2-arylethenyl)oligosilanes, K. Kanno; G. Hamano; R. Honma; S. Kyushin, The 66th Conference of Organometallic Chemistry Japan, 14 Sep. 2019, English, Domestic conference
• Ruthenium-Catalyzed Hydrosilylations Using Hydrodisilane and Alkynes Having Electron-Withdrawing Groups, 菅野研一郎; 小野幸恵; 野口聖矢; 久新荘一郎, 日本化学会春季年会 第98, 2018, Japanese, 船橋市, Domestic conference
• ジヒドロトリシランを用いたアルキンのヒドロシリル化による種々のアルケニルトリシランの合成, 鈴木雄大; 菅野研一郎; 久新荘一郎, 日本化学会関東支部群馬地区研究交流発表会 平成30年度, 2018, Japanese, Domestic conference
• Synthesis of Novel Polysilylated Anthracene Derivatives via Reductive Silylation and Their Reactions, 菅野研一郎; 小荷田 詩歩; 篠原 彩乃; 久新荘一郎, 日本化学会春季年会 第99, 2019, Japanese, 神戸市, Domestic conference
• Ruthenium-Catalyzed Hydrosilylation of 1,3-Dienes with Various Hydrosilanes, 野口聖矢; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第99, 2019, Japanese, 神戸市, Domestic conference
• Ring Inversion of an Organosilicon Belt-Shaped Cyclophane, 藤間佑樹; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第91, 22 Sep. 2011, Japanese, 横浜市, Domestic conference
• アントラセンのBirch型シリル化反応におけるアントラセンの精製と添加物の効果, 喜多光; 菅野研一郎; 久新荘一郎, 第４回CSJ化学フェスタ2014, 2014
• Ruthenium-Catalyzed Alkoxylation Reaction of Hydrooligosilanes, 菅野研一郎; 相川友美; 久新荘一郎, 有機金属化学討論会 第62回, 2015, 大阪市
• Structural Analysis of Mesophases of Silyl-Substituted p-Terphenyls, 南波健史; 大塚恭平; 根岸佑馬; 菅野研一郎; 石田真太郎; 久新荘一郎, CSJ化学フェスタ2015 第5回, 2015, 東京
• Structural Analysis of Mesophases of Silyl-Substituted p-Terphenyls, 南波健史; 大塚恭平; 根岸佑馬; 菅野研一郎; 石田真太郎; 久新荘一郎, 日本化学会春季年会 第96, 2016, 京田辺市
• Ruthenium-Catalyzed Hydrosilylation without Si-Si Bond Cleavage of Hydrooligosilanes, 相川友美; 菅野研一郎; 久新荘一郎, 有機金属化学討論会 第63回, 2016, 東京
• Ruthenium-Catalyzed Z-Selective Hydrosilylation of Alkynes with Preservation of the Si-Si Bonds of Hydrooligosilanes, 野口聖矢; 菅野研一郎; 久新荘一郎, 有機金属化学討論会 第64回, 2017, 仙台市
• Disproportionation reaction of various dihydrodisilanes, 鈴木雄大; 菅野研一郎; 久新荘一郎, CSJフェスタ2017, 2017, 東京
• ルテニウム触媒によるヒドロシリル化反応を用いた種々のビス（アルケニル）テトラおよびヘキサシランの合成と構造, 梶間啓佑; 菅野研一郎; 久新荘一郎, 日本化学会関東支部群馬地区研究交流発表会 平成29年度, 2017
• Synthesis of a Series of Alkenyloligosilanes via Ruthenium-Catalyzed Hydrosilylation of Alkynes without Si-Si Bond Cleavage, 菅野研一郎; 相川友美; 野口聖矢; 梶間啓佑; 小野幸恵; 久新荘一郎, 有機金属化学討論会 第65回, 2018, 京都市
• ルテニウム触媒を用いた種々の1,3-ジエン類のヒドロシリル化反応, 野口聖矢; 菅野研一郎; 久新荘一郎, ケイ素化学協会シンポジウム 第22回, 2018
• Synthesis of Unsymmetrically Functionalized Oligosilanes via Catalytic Partial Reduction of Dichlorooligosilanes, Yuka Niwayama; Ken-ichiro Kanno; Soichiro Kyushin, International Symposium on Element Innovation, The 2nd (Pre ASiS-4 Symposium), 2012, 桐生市
• Synthesis and Properties of 9,9-Dialkoxy-9-silafluorenes, Satoshi Hirose; Ken-ichiro Kanno; Soichiro Kyushin, International Symposium on Element Innovation, The 2nd (Pre ASiS-4 Symposium), 2012, 桐生市
• Stereoselective Synthesis of 9-Alkenyl-10-alkynylanthracene Derivatives via Reductive Silylation and Desilylation, 設楽大介; 代龍之介; 浅見太一; 菅野研一郎; 久新荘一郎, ケイ素化学協会シンポジウム 第17回, 2013, 箱根市
• Stereoselective Synthesis of 9-alkenyl-10-alkynylanthracenes via Reductive Silylation and Desilylation Sequence, Daisuke SHITARA; Ken-ichiro KANNO; Soichiro KYUSHIN, International Conference on Organometallic Chemistry, 26th (ICOMC2014), 2014, 札幌市
• ジルコニウム, またはリチウムを用いたπ共役化合物の選択的合成反応, 菅野研一郎, 産業技術総合研究所環境化学技術研究部門第1回部門セミナー, 19 Jul. 2012, Japanese, Domestic conference
• Synthesis of Unsymmetrically Substituted Oligosilanes via Catalytic Partial Reduction of Dichlorooligosilanes, Ken-ichiro Kanno, Vietnam Malaysia International Chemical Congress (VMICC) 2014, 2014, Hanoi, Vietnam
• Transition Metal Catalyzed Functionalization of Hydrooligosilanes, 相川友美; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第95, 2015, 船橋市
• Activation of Reductive Silylation with Polycyclic Aromatic Compounds, 喜多光; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第95, 2015, 船橋市
• Activation of Reductive Silylation of Anthracene and Other Compounds with Polycyclic Aromatic Compounds, Hikaru Kita; Ken-ichiro Kanno; Soichiro Kyushin, International Symposium on Element Innovation,The 5th, 2015, 桐生市
• Synthesis of Substituted Acene Derivatives via Reductive Silylation Reactions, 菅野研一郎; 喜多 光; 富岡伴幸; 久新荘一郎, 日本化学会春季年会 第96, 2016, 京田辺市
• Synthesis of Unsymmetrically Substituted Oligosilanes via Catalytic Functionalization Reactions, 相川友美; 井野実咲; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第96, 2016, 京田辺市
• Transition Metal-Catalyzed Transformation of Oligosilanes without Si-Si Bond Cleavage, Ken-ichiro Kanno, ISPAC2016 (International Symposium on Pure & Applied Chemistry), 2016, Kuching, Sarawak, Malaysia
• Ruthenium-Catalyzed Hydrosilylation of Alkynes Using Various Hydrooligosilanes without Si-Si Bond Cleavage, 相川友美; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第97, 2017, 横浜市
• Ruthenium-Catalyzed Z-Selective Hydrosilylation of Alkynes without Si?Si Bond Cleavage of Hydrooligosilanes, 野口聖矢; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第97, 2017, 横浜市
• Synthesis and Structures of Various Bis(alkenyl)tetra- and hexasilanes via Ruthenium-Catalyzed Hydrosilylation, 梶間啓佑; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第98, 2018, 船橋市
• Disproportionation Reactions of Various Dihydrodisilanes under Mild Conditions, 鈴木雄大; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第98, 2018, 船橋市
• Ruthenium-Catalyzed Hydrosilylation of 1,3-Dienes, 野口聖矢; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第98, 2018, 船橋市
• Ruthenium-Catalyzed Alkyne Hydrosilylation with Hydrooligosilanes, Ken-ichiro Kanno, ISPAC2017, 2017, Ho-Chi Ming, Vietnam
• アントラセン誘導体の還元的シリル化反応を用いたシリル置換π共役化合物の選択的合成, 菅野研一郎; 浅見太一; 代 龍之介; 久新荘一郎, 第92回日本化学会春季年会, 2012
• 9,9-ジアルコキシ-9-シラフルオレンの合成と反応, 廣瀬 聖; 菅野研一郎; 久新荘一郎, 第92回日本化学会春季年会, 2012
• Synthesis of Unsymmetrically Substituted Oligosilanes via Partial Reductions of Dichloro-, or Dialkoxyoligosilanes, 庭山夕佳; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第92, 2012, 横浜市
• Synthesis of Unsymmetrically Substituted Oligosilanes via Catalytic Partial Reduction of Dichlorooligosilanes, 庭山夕佳; 菅野研一郎; 久新荘一郎, 有機金属化学討論会 第58回, 2012, 吹田市
• 9,9-ジアルコキシ-9-シラフルオレンの合成、構造、および物性, 廣瀬 聖; 菅野研一郎; 久新荘一郎, 平成24年度日本化学会関東支部群馬地区地域懇談会, 2012
• Polysilylation Reaction of Anthracene via Birch-Type Silylation, 菅野研一郎; 小林尚高; 津留崎陽大; 久新荘一郎, 日本化学会春季年会 第93, 2013, 滋賀県草津市
• Synthesis, Photophysical Properties, and Reactions of 9,9-Dialkoxy-9-silafluorenes, 廣瀬聖; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第93, 2013, 滋賀県草津市
• Synthesis of Silyl-Substituted Acenes via Birch-Type Silyllation Reactions, 前村夢美夏; 菅野研一郎; 久新荘一郎, 6th International Symposium on Silicon Science and 2nd International Conference on Advanced Micro-Device Engineering (ISSS&AMDE2010), 2010, 桐生市
• Synthesis of Ladder Polysilanes Having Various Types of Substituents, 新井紘一; 菅野研一郎; 久新荘一郎, 6th International Symposium on Silicon Science and 2nd International Conference on Advanced Micro-Device Engineering (ISSS&AMDE2010), 2010, 桐生市
• Synthesis and Reactions of 2,2,4,4-Tetra-tert-butyl-1,1-dichlorocyclotetrasilane, 安澤英輝; 大塚恭平; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第91, 2011, 横浜市
• Birch-Type Silylation Reaction of Polycyclic Aromatic Compounds, 菅野研一郎; 前村夢美夏; 久新荘一郎, 日本化学会春季年会 第91, 2011, 横浜市
• Synthesis of Polysilane Building Blocks with Various Functional Groups, 新井紘一; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第91, 2011, 横浜市
• 9,10-ジアルキニルアントラセンの還元的シリル化によるビアレン類の合成とその反応, 代龍之介; 浅見太一; 菅野研一郎; 久新荘一郎, 平成２３年度日本化学会関東支部群馬地区懇談会, 2011
• Selective Reduction of Dichlorooligosilanes by Grignard Reagents and Transition Metal Catalysts, 庭山夕佳; 菅野研一郎; 久新荘一郎, ケイ素化学協会シンポジウム 第15回, 2011, 神戸市
• Synthesis, Structures, and Properties of Novel 1-Chloro- and 1,1-Dichlorocyclotetrasilanes, 安澤英輝; 大塚恭平; 菅野研一郎; 久新荘一郎, ケイ素化学協会シンポジウム 第15回, 2011, 神戸市
• Synthesis of Silyl-Substituted p-Conjugated Compounds via Reductive Silylation of Anthracenes, 菅野研一郎; 前村夢美夏; 浅見太一; 久新荘一郎, 有機金属化学討論会 第58回, 2011, 名古屋市
• シリル置換ジインの環化付加反応を用いたシクロファンの選択的合成, 廣瀬 聖; 菅野研一郎; 久新荘一郎, 日本化学会第5回関東支部大会, 2011
• Grignard試薬と遷移金属触媒を用いたジクロロオリゴシランの部分還元反応, 庭山夕佳; 菅野研一郎; 久新荘一郎, 日本化学会第5回関東支部大会, 2011
• Introduction of Silyl Groups on Anthracene via Birch-Type Silylation, Ken-ichiro Kanno; Yumika Maemura; Naotaka Kobayashi; Akihiro Tsurusaki; Soichiro Kyushin, Asian Chemical Congress, The 15th, 2013, Resorts World Sentosa, Singapore
• Synthesis of Silyl-Substituted Biallene Derivatives via Reductive Silylation of 9,10-Dialkynylanthracenes and Their Reactions, 設楽大介; 菅野研一郎; 代龍之介; 浅見太一; 久新荘一郎, 有機金属化学討論会 第60回, 2013, 東京
• 還元的シリル化－脱シリル化を用いたアントラセン誘導体の立体選択的な合成, 設楽大介; 菅野研一郎; 代龍之介; 浅見太一; 久新荘一郎, 第３回CSJ化学フェスタ2013, 2013
• Selective Monoreduction of Dichlorooligosilanes by Grignard Reagents and Transition Metal Catalysts, K. Kanno; Y. Niwayama; S. Kyushin, International Symposium on Catalysis and Fine Chemicals 2013 (C&FC 2013), 2013, Beijing, China
• Synthesis of Silyl-Substituted Anthracenes via Reductive Silylation, K. Kanno, International Symposium on Frontiers of Organometallic Chemistry(Post-Symposium in Peking Univ.), 2013, Beijing, China
• Addition of Silyl Groups to Anthracene via Birch-Type Silylation, 菅野研一郎; 喜多 光; 久新荘一郎, 日本化学会春季年会 第94, 2014, 名古屋市
• Stereoselective Conversion of 9,10-Dialkynylanthracenes via Reductive Silylation, 設楽大介; 菅野研一郎; 久新荘一郎, 日本化学会春季年会 第94, 2014, 名古屋市
• Synthesis of Unsymmetrically Substituted Oligosilanes via Catalytic Selective Monoreduction of Dichlorooligosilanes, K. Kanno; Y. Niwayama; M. Ino; S. Kyushin, International Conference on Organometallic Chemistry, 26th (ICOMC2014), 2014, 札幌市
• Efficiency Improvement of Birch-Type Silylation of Anthracene, 喜多光; 菅野研一郎; 久新荘一郎, 有機金属化学討論会 第61回, 2014, 福岡市
• Intramolecular Cyclization of Silyl-Substituted Diynes Directed toward Regioselective Synthesis of Cyclophanes, Satoshi Hirose; Ken-ichiro Kanno; Soichiro Kyushin, International Symposium on Element Innovation, The 1st, 2011, 桐生市
• Synthesis and Properties of Cyclic Organosilicon Compounds, Toma Yuki; Kanno Ken-ichiro; Kyushin Soichiro, PACIFICHEM 2010, Dec. 2010, English, International conference
• Ruthenium-Catalyzed Selective Monoalkenylation of Ethyl-Substituted Dihydrooligosilanes, 菅野 研一郎; 川和田 優香里; 久新 荘一郎, 日本化学会第102春季年会, 25 Mar. 2022, Japanese
• ルテニウム触媒を用いた第二級シランの再分配反応による第三級シランの合成, 横家穂奈美; 菅野研一郎; 久新荘一郎, 令和3年度日本化学会関東支部 群馬地区 研究交流発表会, 04 Dec. 2021, Japanese
• ルテニウム触媒によるカルボニル化合物とヒドロジシランのヒドロシリル化反応, 須永泰広; 菅野研一郎; 久新荘一郎, 令和3年度日本化学会関東支部 群馬地区 研究交流発表会, 04 Dec. 2021, Japanese
• ルテニウム触媒を用いたヒドロシリル化によるエチル置換ジヒドロオリゴシランの非対称化反応, 川和田 優香里; 菅野 研一郎; 久新 荘一郎, 第81回有機合成化学協会関東支部シンポジウム－群馬・前橋シンポジウム, 27 Nov. 2021, Japanese
• Nickel-Catalyzed Hydrosilylation of Diarylalkynes with a Hydrodisilane, 大塚直紀; 菅野研一郎; 久新荘一郎, 第25回ケイ素化学協会シンポジウム, 28 Oct. 2021
• Synthesis and Properties of Novel Cyano-Substituted σ-π Conjugated Oligosilanes, 三田柾斗; 菅野研一郎; 久新荘一郎, 第25回ケイ素化学協会シンポジウム, 28 Oct. 2021
• Synthesis of Various Alkenyldisilanes by Functional Group Transformation of an Ester Moiety, 江川咲希; 菅野研一郎; 久新荘一郎, 第25回ケイ素化学協会シンポジウム, 28 Oct. 2021
• Desymmetrization of Ethyl-Substituted Dihydrooligosilanes by Ruthenium-Catalyzed Hydrosilylation, 川和田 優香里; 菅野 研一郎; 久新 荘一郎, 第25回ケイ素化学協会シンポジウム, 28 Oct. 2021, Japanese
• ニッケル触媒を用いたヒドロジシランとジアリールアルキンのヒドロシリル化反応, 大塚直紀; 菅野研一郎; 久新荘一郎, 第11回CSJ化学フェスタ2021, 21 Oct. 2021, Japanese
• シアノ基をもつ新規σ–π共役オリゴシランの合成と物性, 三田柾斗; 菅野研一郎; 久新荘一郎, 第11回CSJ化学フェスタ2021, 21 Oct. 2021, Japanese
• エステル部位の官能基変換による様々なアルケニルジシランの合成, 江川咲希; 菅野研一郎; 久新荘一郎, 第11回CSJ化学フェスタ2021, 21 Oct. 2021, Japanese
• Synthesis and Photophysical Properties of Unsymmetrically Functionalized Bis(alkenyl)oligosilanes, 菅野 研一郎; 本間 龍也; 久新 荘一郎, 第67回有機金属化学討論会, 07 Sep. 2021, 2021, English
• ルテニウム触媒を用いたエチル置換ジヒドロオリゴシランとアルキンのヒドロシリル化反応, 川和田 優香里; 菅野 研一郎; 久新 荘一郎, "日本化学会関東支部 群馬地区 研究交流発表会 令和2年度", 05 Dec. 2020, 05 Dec. 2020, 05 Dec. 2020, Japanese
• 種々の対称および非対称ビス(アルケニル)オリゴシランの合成と光物性, 本間 龍也; 菅野 研一郎; 久新 荘一郎, 典型元素化学討論会 第47回, 04 Dec. 2020, 03 Dec. 2020, 05 Dec. 2020, Japanese
• 多環芳香族ユニットをもつ新規アルケニルオリゴシラン誘導体の 合成と光物性, 浜野 銀河; 菅野 研一郎; 久新 荘一郎, ケイ素化学協会シンポジウム 第24回, 06 Nov. 2020, 06 Nov. 2020, 06 Nov. 2020, Japanese
• ルテニウム触媒を用いたエチル置換ジヒドロオリゴシランとアルキンのヒドロシリル化反応, 川和田 優香里; 菅野 研一郎; 久新 荘一郎, CSJフェスタ2020, 22 Oct. 2020, 20 Oct. 2020, 22 Oct. 2020, Japanese
• 種々の対称および非対称ビス(アルケニル)テトラシランの合成と光物性, 本間 龍也; 菅野 研一郎; 久新 荘一郎, 日本化学会春季年会 第100, 22 Mar. 2020, 22 Mar. 2020, 25 Mar. 2020, Japanese
• 多環芳香族置換基をもつ新規アルケニルオリゴシラン誘導体の合成と光物性, 浜野 銀河; 菅野 研一郎; 久新 荘一郎, 日本化学会春季年会 第100, 22 Mar. 2020, 22 Mar. 2020, 25 Mar. 2020, Japanese
• 種々のビス（アルケニル）テトラシランの合成、構造、光物性, 本間龍也; 菅野研一郎; 久新荘一郎, ケイ素化学協会シンポジウム 第23回, 01 Nov. 2019, 01 Nov. 2019, 02 Nov. 2019, Japanese
• ルテニウム触媒を用いた多環式芳香族置換基をもつ新規テトラシラン誘導体の合成，構造，性質, 浜野銀河; 菅野研一郎; 久新荘一郎, ケイ素化学協会シンポジウム 第23回, 01 Nov. 2019, 01 Nov. 2019, 02 Nov. 2019, Japanese
• 種々のビス（アルケニル）テトラシランの合成、構造、光物性, 本間龍也; 菅野研一郎; 久新荘一郎, CSJフェスタ2019, 16 Oct. 2019, 15 Oct. 2019, 19 Oct. 2019, Japanese
• ルテニウム触媒を用いた多環芳香族置換基をもつ新規テトラシラン誘導体の合成、構造、性質, 浜野銀河; 菅野研一郎; 久新荘一郎, CSJフェスタ2019, 16 Oct. 2019, 15 Oct. 2019, 19 Oct. 2019, Japanese

Industrial Property Rights

• Patent right, 特願2006-052927, 28 Feb. 2006, 特開2007-013097, 18 Jan. 2007
• Patent right, 特願2002-366801, 18 Dec. 2002, 特開2004-196943, 15 Jul. 2004, 特許第3880514号, 17 Nov. 2006
• Patent right, 特願2004-065824, 09 Mar. 2004, 特開2005-255547, 22 Sep. 2005, 特許第4695845号, 04 Mar. 2011
• Patent right, 特願2005-064424, 08 Mar. 2005, 特開2006-248923, 21 Sep. 2006, 特許第4787953号, 29 Jul. 2011
• Patent right, 特願2005-064442, 08 Mar. 2005, 特開2006-248924, 21 Sep. 2006, 特許第4787954号, 29 Jul. 2011
• Patent right, 特願2012-503292, 04 Mar. 2011, 特許第5697106号, 20 Feb. 2015
• Patent right, 特願2010-166479, 23 Jul. 2010, 特開2012-025700, 09 Feb. 2012
• Patent right, 特願2010-545792, 08 Jan. 2010, 特許第5582648号, 25 Jul. 2014
• Patent right, 特願2009-137699, 08 Jun. 2009, 特開2010-280641, 16 Dec. 2010
• Patent right, 特願2009-024330, 04 Feb. 2009, 特開2010-180151, 19 Aug. 2010
• Patent right, 特願2009-022767, 03 Feb. 2009, 特開2010-180140, 19 Aug. 2010, 特許第5455110号, 17 Jan. 2014
• Patent right, 特願2013-271039, 27 Dec. 2013, 特開2014-159405, 04 Sep. 2014, 特許第5704771号, 06 Mar. 2015
• Patent right, Biphenylenecyclobutenylene polymers for electroluminescent devices and their manufacture
• Patent right, Preparation of acenaphthylenes from dihalonaphthalenes and acetylenes
• Patent right, Preparation of acenes by selective elimination of substituents from condensed cyclic compounds and subsequent aromatization
• Patent right, Preparation of acenes by isomerization of exocyclic dienes with Lewis acids

Awards

• 2010

Research Projects

• Jun. 2008, Jun. 2008, Principal investigator, Competitive research funding
• Apr. 2008, Mar. 2009, Principal investigator, Competitive research funding
• Apr. 2011, Principal investigator, Competitive research funding
• Development of Novel Synthetic Reactions of Oligosilanes using Transition Metal Complexes, 菅野 研一郎, Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (C), 2014, 2017, Principal investigator, Competitive research funding
• Development of Novel Silicon-Silicon Bond Formation Reaction with Transition Metal Complexes, 菅野 研一郎, Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (C), Grant-in-Aid for Scientific Research (C), Gunma University, 2011, 2014, Principal investigator, The transition metal-catalyzed monoreduction of dichlorooligosianes with alkyl Grignard reagents proceeds with high selectivity to afford the corresponding chloro(hydro)oligosilanes in good yields. The satisfactory results were obtained from the reactions with the primary or secondary alkyl Grignard reagents, whereas that with the tertiary alkyl Grignard reagents proceed very sluggishly. Thus obtained chloro(hydro)oligosilanes were successfully introduced a variety of organic substituents by means of the corresponding organolithium or Grignard reagents. These results shows the importance of this method to supply the building blocks for organosilicon clusters., Competitive research funding, 23550044

  対象リソースIRI
• Unusual Reactions of the Indenyl Ligand on Zirconium and their Applications in Organic Synthesis, 高橋 保, Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (C), Grant-in-Aid for Scientific Research (C), Hokkaido University, 2008, 2011, The indenyl ligand or cyclopentadienyl ligand have been believed as 'inert'. However, in this project, the indenyl ligand of bis(indenyl)zirconacyclopentadienes coupled with diene moiety in the same molecule to give fluorene derivatives in good yields. The size of the substituents on the cyclopentadienyl ligand effects the coupling greatly. The reaction of bis(cyclopentadienyl)zirconacyclopentadienes with titanium chloride gave low yield of the coupling product. However, in the t-butyl cyclopentadienyl ligand issue, the yield was quite high., Competitive research funding, 20550090

  対象リソースIRI
• Development of Efficient Synthetic Method of Oligoenes via Selective Linear Oligomerization of Alkynes, 菅野 研一郎, Japan Society for the Promotion of Science, Grant-in-Aid for Young Scientists (B), Grant-in-Aid for Young Scientists (B), Hokkaido University, 2008, 2010, Principal investigator, Highly selective synthesis of tri-and tetraene derivatives as single products was achieved via linear oligomerization of different alkynes via a zirconocene and copper-mediated reaction. And, interesting 7-membered-ring formation of a triene derivatives obtained from the above-mentioned reaction was found. These reactions were applicable for variously substituted substrates., Competitive research funding, 20750160

  対象リソースIRI
• Synthesis and Reactivity of Thermally Stable Zirconocene (II) Species Precursors, 高橋 保, Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (C), Grant-in-Aid for Scientific Research (C), Hokkaido University, 2006, 2008, Reactions of tris (indenyl) zirconium hydride with a variety of alkynes were investigated and evaluated the reactivity of the zirconium complex as zirconocen (II) equivalent. The reaction of tris (indenyl) zirconium hydride with internal alkynes afforded the corresponding zirconacyclopentadienes in high yields. Interestingly, the reaction with terminal arylalkynes produced the2,5-diarylzirconacycles with high selectivity. A reaction of thus obtained bis (indenyl) zirconacyclopentadienes with titanium tetrachloride afforded the corresponding fluorene derivatives via coupling of the diene moiety with the indenyl ligand. This reaction was applicable for alkyl-or aryl-substituted, and bicyclic zirconacyclopentadienes and furnished the substituted fluorenes. Instead of the indenyl ligand, zirconacyclopentadienes having substituted cyclopentadienyl ligands were also applied for the reaction and afforded the corresponding indene derivatives. A comparison of the structural parameters of the zirconacyclopentadienes with the related ones suggested that the coupling reactivity was strongly affected by the distance between the indenyl or cyclopentadienyl ligands and the diene moiety of the zirconacyclopentadienes. The most reactive titanacyclopentadienes have the shortest distance. In addition, the reactivity was increased with increasing the steric bulkiness of the ligand. Titanium tetrachloride played an important role as an oxidant in the reaction., Competitive research funding, 18550089

  対象リソースIRI
• Development of Novel Synthetic Methods by Cooperative Use of Metalacycles and Late Transition Metal Catalysts, 高橋 保, Japan Society for the Promotion of Science, Grant-in-Aid for Scientific Research (C), Grant-in-Aid for Scientific Research (C), Hokkaido University, 2004, 2006, In this work, we have developed novel synthetic methods of unsaturated organic compounds by metalacycles and late transition-metal catalysts. With zirconacyclopentadienes and nickel complexes, catalytic synthetic methods of benzene and polycyclic aromatic compounds were found and developed. Moreover, copper-catalyzed synthesis of diallenes from reactions of zirconacyclopentanes with propargyl halides was developed. It was found that a series of nickel-catalyzed cycloaddition reactions of zirconacyclopentadienes with alkenes and alkynes. In the presence of a catalytic amount of nickel(II) chloride bis(triphenylphosphine), a zirconacyclopentadiene reacted with 2 equiv of 1-haloalkyne or allyl halide to afford the corresponding alkynylbenzene or pentasubstituted benzene, respectively. This is striking contrast to the reaction with copper(I) chloride as a catalyst, which produced the corresponding bis(alkynyl)butadiene. It was developed that coupling reactions of zirconacyclopentadienes and 1,2-dihalobenzenens mediated or catalyzed by nickel complexes to afford the corresponding polycyclic compounds. By the precedent method of the coupling reaction which is mediated by copper(I) chloride, the applicable dihaloarenes were limited for the diiodo- or bromoiodoarenes. Substitution of copper(I) to nickel(0) complex, however, raised the reactivity of the zirconacycles toward dibromo- and even dichlorobenzenes. Furthermore, the use of 3-(trifluoromethyl)styrene improved the reaction for the nickel-catalyzed one. That is, in the presense of 10 mol% of Ni(cod)_2 and 20 mol% of PPh_3, the reaction of a zirconacyclopentadiene with 1,2-dihalobenzene afforded the corresponding naphthalene in a good yield. The method was applied for various zirconacyclopentadienes and dihalobenzenes. Reactions of zirconacyclopentanes with propargyl halides in the presence of copper(I) salt were investigated. In the presence of copper(I) chloride, zirconacyclopentanes reacted with two equivalents of a propargyl halide to give bisallenylation products in moderate to high yields. By controlling the amount of CuCl, stepwise allenylation was achieved and a variety of unsymmetrically substituted diallene derivatives were prepared as well., Competitive research funding, 16550088

  対象リソースIRI
• Development of Synthetic Methods of Organosilicon Compounds by Transition-Metal Complexes, Grants and Funding, 2010, Competitive research funding