Researcher Profile and Settings

Researcher

• Name

  AMII Hideki

Profile and Settings

• Name

  Amii, Hideki

Alternate Names

• Hiideki Amii

Affiliation

• Gunma University, Professor
• Gunma University, Professor

Degree

• Doctor of Engineering
• Doctor of Engineering
• Doctor of Engineering

Association Memberships

• American Chemical Society
• Royal Society of Chemistry
• Apr. 2010, Mar. 2020

Research Experience

• Gunma University, Professor, Prof lv
• Gunma University Graduate School of Engineering, Course of Chemistry and Chemical Biology
• Gunma University
• Former Institution / Organization Graduate School of Science, Kobe University, Associate Professor, Associate prof lecturer lv

Research Activities

Research Areas

• Nanotechnology/Materials, Synthetic organic chemistry

Research Interests

• Organic Chemistry

Published Papers

• alpha-Trifluoromethylated carbanion synthons, Kenji Uneyama; Toshimasa Katagiri; Hiideki Amii, Jul. 2008, ACCOUNTS OF CHEMICAL RESEARCH, 41, 7, 817, 829

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• Selective aromatic carbon-oxygen bond cleavage of trifluoromethoxyarenes: a trifluoromethoxy group as a convertible directing group, Akinori Iijima; Hideki Amii, Oct. 2008, TETRAHEDRON LETTERS, 49, 41, 6013, 6015, Scientific journal

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• Boron-substituted difluorocyclopropanes: New building blocks of gem-difluorocyclopropanes, Yasutaka Fujioka; Hideki Amii, Mar. 2008, ORGANIC LETTERS, 10, 5, 769, 772, Scientific journal

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• Difluorinated Danishefsky's diene: A versatile C-4 building block for the fluorinated six-membered rings, H Amii; T Kobayashi; H Terasawa; K Uneyama, Oct. 2001, ORGANIC LETTERS, 3, 20, 3103, 3105, Scientific journal

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• Rh(I)-catalyzed coupling cyclization of N-aryl trifluoroacetimidoyl chlorides with alkynes: One-pot synthesis of fluorinated quinolines, H Amii; Y Kishikawa; K Uneyama, Apr. 2001, ORGANIC LETTERS, 3, 8, 1109, 1112, Scientific journal
• A trial toward the synthesis of gamma-fluorinated beta-amino-alpha-thiohydroxyamino acid: A finding of desulfurizative C-C bond formation in thio-Wittig-type rearrangement of S-(N-aryltrifluoroacetimidoyl)thioglycolates, K Uneyama; H Ohkura; J Hao; H Amii, Feb. 2001, JOURNAL OF ORGANIC CHEMISTRY, 66, 3, 1026, 1029, Scientific journal

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• An Origin of Complicated Infrared Spectra of Perfluoroalkyl Compounds Involving a Normal Alkyl Group, Takeshi Hasegawa; Takafumi Shimoaka; Yuki Tanaka; Nobutaka Shioya; Kohei Morita; Masashi Sonoyama; Hideki Amii; Toshiyuki Takagi; Toshiyuki Kanamori, Jun. 2015, CHEMISTRY LETTERS, 44, 6, 834, 836, Scientific journal

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• Enhancement of stereoselectivities in asymmetric synthesis using fluorinated solvents, auxiliaries, and catalysts, Tsuyuka Sugiishi; Masato Matsugi; Hiromi Hamamoto; Hideki Amii, 2015, RSC ADVANCES, 5, 22, 17269, 17282

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• Carbon-carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylations, Tsuyuka Sugiishi; Hideki Amii; Kohsuke Aikawa; Koichi Mikami, Dec. 2015, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 11, 2661, 2670, Scientific journal

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• Highly Controlled Ring-Opening of Siloxydifluorocyclopropanes: A Versatile Route to Cyclic Fluoroketones, Yoshiya Kageshima; Chiharu Suzuki; Kojun Oshiro; Hideki Amii, Jan. 2015, SYNLETT, 26, 1, 63, 66, Scientific journal

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• C-F Bond Activation in Organic Synthesis, Hideki Amii; Kenji Uneyama, May 2009, CHEMICAL REVIEWS, 109, 5, 2119, 2183

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• Non-ideal mixing of dimyristoylphosphatidylcholine with its partially fluorinated analogue in hydrated bilayers, Hiroshi Takahashi; Masaru Yoshino; Toshiyuki Takagi; Hideki Amii; Teruhiko Baba; Toshiyuki Kanamori; Masashi Sonoyama, Feb. 2013, CHEMICAL PHYSICS LETTERS, 559, 107, 111, Scientific journal

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• Physicochemical Studies of Bacteriorhodopsin Reconstituted in Partially Fluorinated Phosphatidylcholine Bilayers, Masaru Yoshino; Takashi Kikukawa; Hiroshi Takahashi; Toshiyuki Takagi; Yasunori Yokoyama; Hideki Amii; Teruhiko Baba; Toshiyuki Kanamori; Masashi Sonoyama, May 2013, JOURNAL OF PHYSICAL CHEMISTRY B, 117, 18, 5422, 5429, Scientific journal

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• Flow microreactor synthesis in organo-fluorine chemistry, Hideki Amii; Aiichiro Nagaki; Jun-ichi Yoshida, Dec. 2013, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 9, 2793, 2802

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• Formation and structure of a fluorinated [2.2]paracyclophan-1-ene, Hideki Amii; Ryotaro Hayashi; Motoharu Seo; Yukako Katahira; Akira Kobayashi; Kenji Uneyama, Aug. 2013, JOURNAL OF FLUORINE CHEMISTRY, 152, 90, 93, Scientific journal

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• Sodium Bromodifluoroacetate: A Difluorocarbene Source for the Synthesis of gem-Difluorocyclopropanes, Kojun Oshiro; Yoshimichi Morimoto; Hideki Amii, Jun. 2010, SYNTHESIS-STUTTGART, 12, 2080, 2084, Scientific journal

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• Novel Axially Chiral Phosphine Ligand with a Fluoro Alcohol Moiety for Rh-Catalyzed Asymmetric Arylation of Aromatic Aldehydes, Satoshi Morikawa; Kyosuke Michigami; Hideki Amii, Jun. 2010, ORGANIC LETTERS, 12, 11, 2520, 2523, Scientific journal

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• An improved synthesis of fluorinated imidoylsilanes, Chie Akamatsu; Atsushi Yamauchi; Takeshi Kobayashi; Yu Ozeki; Jun Takagi; Hideki Amii; Kenji Uneyama, Jun. 2006, SYNTHESIS-STUTTGART, 11, 11, 1836, 1840, Scientific journal

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• Synthesis of 3,3,4,4-tetrafluoro-1,2-bis(imino)cyclobutanes: A cyclic version of fluorinated alpha-diimines, Hideki Amii; Mitsuhiro Kohda; Toshimasa Katagiri; Kenji Uneyama, May 2006, JOURNAL OF FLUORINE CHEMISTRY, 127, 4-5, 505, 509, Scientific journal

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• Rhodium(I)-catalyzed successive double cleavage of carbon-carbon bonds of strained spiro cyclobutanones, M Murakami; K Takahashi; H Amii; Y Ito, Oct. 1997, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 119, 39, 9307, 9308, Scientific journal
• THEORETICAL-STUDY ON THE REACTION-MECHANISM AND REGIOSELECTIVITY OF SILASTANNATION OF ACETYLENES WITH A PALLADIUM CATALYST, M HADA; Y TANAKA; M ITO; M MURAKAMI; H AMII; Y ITO; H NAKATSUJI, Sep. 1994, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 116, 19, 8754, 8765, Scientific journal
• A study on ligand-coupling reactions of imidoyl palladium complexes, Masashi Morishita; Hideki Amii, Jan. 2007, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692, 1-3, 620, 624, Scientific journal

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• Selective defluorination approach to N-cbz-3,3-difluoro-2-difluoromethylenepyrrolidine and its application to 3,3-difluoroproline dipeptide synthesis, Yong Guo; Kana Fujiwara; Hideki Amii; Kenji Uneyama, Oct. 2007, JOURNAL OF ORGANIC CHEMISTRY, 72, 22, 8523, 8526

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• A REMARKABLE EFFECT OF SILYL SUBSTITUTION ON ELECTROCYCLIZATION OF VINYLALLENES, M MURAKAMI; H AMII; K ITAMI; Y ITO, Jul. 1995, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 34, 13-14, 1476, 1477, Scientific journal
• A rich chemistry of fluorinated imidoyl halides, K Uneyama; H Amii; T Katagiri; T Kobayashi; T Hosokawa, Feb. 2005, JOURNAL OF FLUORINE CHEMISTRY, 126, 2, 165, 171, Scientific journal

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• Mg-0-promoted selective C-F bond cleavage of trifluoromethyl ketones: a convenient method for the synthesis of 2,2-difluoro enol silanes, H Amii; T Kobayashi; Y Hatamoto; K Uneyama, Jul. 1999, CHEMICAL COMMUNICATIONS, 14, 1323, 1324, Scientific journal
• An Efficient Route to Difluoromethylated Pyridines, Kenichi Fujikawa; Akira Kobayashi; Hideki Amii, Oct. 2012, SYNTHESIS-STUTTGART, 44, 19, 3015, 3018, Scientific journal

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• Preparation, Structure, and Reactions of Trifluoroacetimidoyl Palladium(II) Complexes, Hideki Amii; Katsuhiko Kageyama; Yosuke Kishikawa; Tsuyoshi Hosokawa; Ryo Morioka; Toshimasa Katagiri; Kenji Uneyama, Feb. 2012, ORGANOMETALLICS, 31, 4, 1281, 1286, Scientific journal

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• New approaches to stereoselective synthesis of fluorinated amino acids, K Uneyama; T Katagiri; H Amii, Nov. 2002, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 60, 11, 1069, 1075, Scientific journal
• Singlet diradicals: from transition states to crystalline compounds, D Scheschkewitz; H Amii; H Gornitzka; WW Schoeller; D Bourissou; G Bertrand, Mar. 2002, SCIENCE, 295, 5561, 1880, 1881, Scientific journal
• A review of Mg metal-promoted C-F bond activation; a reliable synthetic approach to difluorinated organic compounds, K Uneyama; H Amii, Apr. 2002, JOURNAL OF FLUORINE CHEMISTRY, 114, 2, 127, 131, Scientific journal
• A facile synthesis of difluoromethylaziridines, M Mae; M Matsuura; H Amii; K Uneyama, Mar. 2002, TETRAHEDRON LETTERS, 43, 11, 2069, 2072, Scientific journal
• A new sequential defluorination route to alpha-fluoro-alpha,beta-unsaturated ketones from trifluoromethyl ketones, H Hata; T Kobayashi; H Amii; K Uneyama; JT Welch, Aug. 2002, TETRAHEDRON LETTERS, 43, 35, 6099, 6102, Scientific journal
• Mg-promoted double silylation of trifluoroacetimidoyl chlorides. A new entry to the fluorinated dianion equivalents, T Kobayashi; T Nakagawa; H Amii; K Uneyama, Nov. 2003, ORGANIC LETTERS, 5, 23, 4297, 4300, Scientific journal

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• Unusual reactions of N-allylic difluoroenamines under thermal conditions, H Amii; Y Ichihara; T Nakagawa; T Kobayashi; K Uneyama, 2003, CHEMICAL COMMUNICATIONS, 23, 2902, 2903, Scientific journal

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• A new finding in selective Baeyer-Villiger oxidation of alpha-fluorinated ketones; a new and practical route for the synthesis of alpha-fluorinated esters, S Kobayashi; H Tanaka; H Amii; K Uneyama, Feb. 2003, TETRAHEDRON, 59, 9, 1547, 1552, Scientific journal

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• A novel route to the fluorinated diimines: carbon monoxide-promoted reductive homocoupling of fluorinated imidoyl iodides in the presence of a palladium catalyst, H Amii; M Kohda; M Seo; K Uneyama, 2003, CHEMICAL COMMUNICATIONS, 14, 1752, 1753, Scientific journal

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• Oxidative cross-coupling of beta,beta-difluoroenol silyl ethers with nucleophiles: A dipole-inversion method to difluoroketones, K Uneyama; H Tanaka; S Kobayashi; M Shioyama; H Amii, Aug. 2004, ORGANIC LETTERS, 6, 16, 2733, 2736, Scientific journal

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• Catalytic route to the synthesis of optically active beta,beta-difluoroglutamic acid and beta,beta-difluoroproline derivatives, A Suzuki; M Mae; H Amii; K Uneyama, Jul. 2004, JOURNAL OF ORGANIC CHEMISTRY, 69, 15, 5132, 5134, Scientific journal

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• Radical-type reactivity of the 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyl, H Amii; L Vranicar; H Gornitzka; D Bourissou; G Bertrand, Feb. 2004, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 126, 5, 1344, 1345, Scientific journal

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• New domino sequences involving successive cleavage of carbon-carbon and carbon-oxygen bonds: Discrete product selection dictated by catalyst ligands, M Murakami; T Itahashi; H Amii; K Takahashi; Y Ito, Sep. 1998, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 120, 38, 9949, 9950, Scientific journal
• Novel intramolecular rearrangement of 3-bromo-3,3-difluoroalanine Schiff bases via radical ipso-substitution at the aromatic ring, H Amii; S Kondo; K Uneyama, Sep. 1998, CHEMICAL COMMUNICATIONS, 17, 1845, 1846, Scientific journal
• Surface properties of a single perfluoroalkyl group on water surfaces studied by surface potential measurements, Takafumi Shimoaka; Yuki Tanaka; Nobutaka Shioya; Kohei Morita; Masashi Sonoyama; Hideki Amii; Toshiyuki Takagi; Toshiyuki Kanamori; Takeshi Hasegawa, Dec. 2016, JOURNAL OF COLLOID AND INTERFACE SCIENCE, 483, 353, 359, Scientific journal

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• Lateral Diffusion and Molecular Interaction in a Bilayer Membrane Consisting of Partially Fluorinated Phospholipids, Yoshiaki Okamoto; Toshinori Motegi; Kohei Morita; Toshiyuki Takagi; Hideki Amii; Toshiyuki Kanamori; Masashi Sonoyama; Ryugo Tero, Oct. 2016, LANGMUIR, 32, 41, 10712, 10718, Scientific journal

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• DOUBLE ISOMERIZATION POLYMERIZATION OF BISPSEUDOUREAS - A NEW CYCLOPOLYMERIZATION, M MIYAMOTO; H AMII; K AOI; T SAEGUSA, Mar. 1993, MACROMOLECULES, 26, 6, 1474, 1479, International conference proceedings
• SYNTHESIS OF ACYLSILANES VIA SILASTANNATION OF ALKYNES BY A PALLADIUM ISOCYANIDE CATALYST, M MURAKAMI; H AMII; N TAKIZAWA; Y ITO, Oct. 1993, ORGANOMETALLICS, 12, 10, 4223, 4227
• A novel intramolecular defluorinative cyclization approach to the synthesis of difluoromethylated quinazolic acid derivatives, J Hao; H Ohkura; H Amii; K Uneyama, 2000, CHEMICAL COMMUNICATIONS, 19, 1883, 1884, Scientific journal
• Preparation and thermal behavior of 3,3,4,4-tetrafluorocyclobutane-1,2-diols: A new family of cyclobutane-1,2-diols, S Kobayashi; Y Yamamoto; H Amii; K Uneyama, Dec. 2000, CHEMISTRY LETTERS, 29, 12, 1366, 1367, Scientific journal
• Palladium-catalyzed tert-butoxycarbonylation of trifluoroacetimidoyl iodides, H Amii; Y Kishikawa; K Kageyama; K Uneyama, Jun. 2000, JOURNAL OF ORGANIC CHEMISTRY, 65, 11, 3404, 3408, Scientific journal
• A practical and highly efficient synthesis of alpha-(trimethylsilyl)-difluoroacetates, H Amii; T Kobayashi; K Uneyama, Dec. 2000, SYNTHESIS-STUTTGART, 14, 2001, 2003, Scientific journal
• Reactions of benzeneselenenyl fluoride generated by XeF2-(PhSe)(2) system with electron-deficient alkenes, K Uneyama; S Hiraoka; H Amii, Mar. 2000, JOURNAL OF FLUORINE CHEMISTRY, 102, 1-2, 215, 218, Scientific journal
• A New Method for Aromatic Difluoromethylation: Copper-Catalyzed Cross-Coupling and Decarboxylation Sequence from Aryl Iodides, Kenichi Fujikawa; Yasutaka Fujioka; Akira Kobayashi; Hideki Amii, Oct. 2011, ORGANIC LETTERS, 13, 20, 5560, 5563, Scientific journal

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• Copper-Catalyzed Aromatic Trifluoromethylation via Group Transfer from Fluoral Derivatives, Hideaki Kondo; Masahiro Oishi; Kenichi Fujikawa; Hideki Amii, May 2011, ADVANCED SYNTHESIS & CATALYSIS, 353, 8, 1247, 1252, Scientific journal

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• Perfluoroalkylation in flow microreactors: generation of perfluoroalkyllithiums in the presence and absence of electrophiles, Aiichiro Nagaki; Shinya Tokuoka; Shigeyuki Yamada; Yutaka Tomida; Kojun Oshiro; Hideki Amii; Jun-ichi Yoshida, 2011, ORGANIC & BIOMOLECULAR CHEMISTRY, 9, 21, 7559, 7563, Scientific journal

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• Breaking of the C-C bond of cyclobutanones by rhodium(I) and its extension to catalytic synthetic reactions, M Murakami; H Amii; K Shigeto; Y Ito, Sep. 1996, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 118, 35, 8285, 8290, Scientific journal
• Efficient Generation and Increased Reactivity in Cationic Gold via Bronsted Acid or Lewis Acid Assisted Activation of an Imidogold Precatalyst, Junbin Han; Naoto Shimizu; Zhichao Lu; Hideki Amii; Gerald B. Hammond; Bo Xu, Jul. 2014, ORGANIC LETTERS, 16, 13, 3500, 3503, Scientific journal

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• Trifluoroethoxy-Coated Phthalocyanine Catalyzes Perfluoroalkylation of Alkenes under Visible-Light Irradiation, Kohei Matsuzaki; Tomoya Hiromura; Hideki Amii; Norio Shibata, Jul. 2017, MOLECULES, 22, 7, 1130, Scientific journal

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• Predicting Counterion Effects Using a Gold Affinity Index and a Hydrogen Bonding Basicity Index, Zhichao Lu; Junbin Han; Otome E. Okoromoba; Naoto Shimizu; Hideki Amii; Claudio F. Tormena; Gerald B. Hammond; Bo Xu, Nov. 2017, ORGANIC LETTERS, 19, 21, 5848, 5851, Scientific journal

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• Study of Perfluoroalkyl Chain-Specific Band Shift in Infrared Spectra on the Chain Length, Takafumi Shimoaka; Masashi Sonoyama; Hideki Amii; Toshiyuki Takagi; Toshiyuki Kanamori; Takeshi Hasegawa, Nov. 2017, JOURNAL OF PHYSICAL CHEMISTRY A, 121, 44, 8425, 8431, Scientific journal

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• A Convenient Method for Catalytic Aromatic Pentafluoroethylation Using Potassium (Pentafluoroethyl)trimethoxyborate, Tsuyuka Sugiishi; Daisuke Kawauchi; Mizuki Sato; Tatsuya Sakai; Hideki Amii, Apr. 2017, SYNTHESIS-STUTTGART, 49, 8, 1874, 1878, Scientific journal

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• Fluorous Property of a Short Perfluoroalkyl-Containing Compound Realized by Self-Assembled Monolayer Technique on a Silicon Substrate, Kise, Ryuma; Fukumi, Aki; Shioya, Nobutaka; Shimoaka, Takafumi; Sonoyama, Masashi; Amii, Hideki; Takagi, Toshiyuki; Kanamori, Toshiyuki; Eda, Kazuo; Hasegawa, Takeshi, Apr. 2019, BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 92, 4, 785, 789, Scientific journal

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• Raman Optical Activity on a Solid Sample: Identification of Atropisomers of Perfluoroalkyl Chains Having a Helical Conformation and No Chiral Center, Shimoaka, Takafumi; Sonoyama, Masashi; Amii, Hideki; Takagi, Toshiyuki; Kanamori, Toshiyuki; Hasegawa, Takeshi, May 2019, JOURNAL OF PHYSICAL CHEMISTRY A, 123, 18, 3985, 3991, Scientific journal

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• A novel synthesis of beta-trifluoromethyl-substituted isoserine via intramolecular rearrangement of imino ethers, K Uneyama; JA Hao; H Amii, Jun. 1998, TETRAHEDRON LETTERS, 39, 23, 4079, 4082, Scientific journal
• Pd-catalyzed asymmetric hydrogenation of alpha-fluorinated iminoesters in fluorinated alcohol: A new and catalytic enantioselective synthesis of fluoro alpha-amino acid derivatives, H Abe; H Amii; K Uneyama, Feb. 2001, ORGANIC LETTERS, 3, 3, 313, 315, Scientific journal

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• Thermotropic transition behaviors of novel partially fluorinated dimyristoylphosphatidylcholines with different perfluoroalkyl chain lengths, Morita Kohei; Horikoshi Miki; Yanagi Tamami; Takagi Toshiyuki; Takahashi Hiroshi; Amii Hideki; Hasegawa Takeshi; Sonoyama Masashi, Sep. 2019, Chem. Lett., 48, 9, 1105, 1108, Scientific journal

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• Comparison of two different partially fluorinated phosphatidylcholines with perfluorobutyl group on thermotropic properties of bilayer membrane and reconstituted bacteriorhodopsin, Yanagi, T; Takagi, T; Takahashi, H; Kikukawa, T; Amii, H; Sonoyama, M, Jun. 2019, Biophys. Rev., 11, 3, 395, 398, Scientific journal

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• Stability of the two-dimensional lattice of bacteriorhodopsin reconstituted in partially fluorinated phosphatidylcholine bilayers, Hiroshi Takahashi; Masaru Yoshino; Kohei Morita; Toshiyuki, Takagi; Yasunori Yokoyama; Takashi; Kikukawa; Hideki Amii; Toshiyuki Kanamori; Masashi Sonoyama, Mar. 2019, Biochimica et Biophysica Acta (BBA) - Biomembranes, 1861, 3, 631, 642, Scientific journal

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• Solvent-Promoted Catalyst-Free Nucleophilic Fluoroalkylation of Aldehydes, Kazuki Komoda; Ai Shimokawa; Hideki Amii, Feb. 2019, ChemistrySelect, 4, 2374, 2378, Scientific journal

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• Copper-Promoted Cross-Coupling Reactions for the Synthesis of Aryl(difluoromethyl)phosphonates Using Trimethylsilyl(difluoromethyl)phosphonate, Komoda, Kazuki; Iwamoto, Rei; Kasumi, Masakazu; Amii, Hideki, Dec. 2018, Molecules, 23, 12, 3292, Scientific journal
• Nucleophilic fluoroalkylation/cyclization route to fluorinated phthalides, Masanori Inaba; Tatsuya Sakai; Shun Shinada; Tsuyuka Sugiishi; Yuta Nishina; Norio Shibata; Hideki Amii, 19 Jan. 2018, Beilstein Journal of Organic Chemistry, 14, 182, 186, Scientific journal

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• Enolate-based strategies to construct gem-Difluoromethylene Compounds, Hideki Amii, 2017, Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 75, 11, 1125, 1132, Scientific journal

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• Trifluoromethylation of aryl iodides catalyzed by the copper(I)-phen complex, Naoto Shimizu; Hideaki Kondo; Masahiro Oishi; Kenichi Fujikawa; Kazuki Komoda; Hideki Amii, 2016, Organic Syntheses, 93, 147, 162, Scientific journal

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• Aromatic trifluoromethylation catalytic in copper, Masahiro Oishi; Hideaki Kondo; Hideki Amii, 2009, CHEMICAL COMMUNICATIONS, 109, 14, 1909, 1911, Scientific journal

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• The catalytic version of stoichiometric organic synthesis, H Amii, Feb. 2005, LETTERS IN ORGANIC CHEMISTRY, 2, 1, 5, 14
• alpha-bond stretching: A static approach for dynamic process, D Scheschkewitz; H Amii; H Gornitzka; WW Schoeller; D Bourissou; G Bertrand, 2004, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 43, 5, 585, 587, Scientific journal

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• New C-F bond-cleavage route for the synthesis of octafluoro[2.2]paracyclophane, H Amii; Y Hatamoto; M Seo; K Uneyama, Oct. 2001, JOURNAL OF ORGANIC CHEMISTRY, 66, 21, 7216, 7218, Scientific journal
• First synthesis of 3,3-difluoroserine and cysteine derivatives via Mg(0)-promoted selective C-F bond cleavage of trifluoromethylimines, M Mae; H Amii; K Uneyama, Oct. 2000, TETRAHEDRON LETTERS, 41, 41, 7893, 7896, Scientific journal
• SELECTIVE ACTIVATION OF CARBON-CARBON BONDS NEXT TO A CARBONYL GROUP, M MURAKAMI; H AMII; Y ITO, Aug. 1994, NATURE, 370, 6490, 540, 541, Scientific journal
• Synthesis of 3-fluoro-2,5-disubstituted furans through ring expansion of gem-difluorocyclopropyl ketones, Tsuyuka Sugiishi; Chihori Matsumura; Hideki Amii, 2020, Organic & Biomolecular Chemistry, 18, 18, 3459, 3462, Scientific journal

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• Effect of partial fluorination in the myristoyl groups on thermal and interfacial properties of dimyristoylphosphatidylcholine, Masaru Yoshino; Hiroshi Takahashi; Toshiyuki Takagi; Teruhiko Baba; Kohei Morita; Hideki Amii; Toshiyuki Kanamori; Masashi Sonoyama, 2012, Chemistry Letters, 41, 11, 1495, 1497, Scientific journal

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• Recent Progress in Catalytic Aromatic Trifluoromethylation, Hideki Amii, Jul. 2011, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 69, 7, 752, 762, Scientific journal
• Fast-track computational access to reaction mechanisms provides comprehensive insights into aminolysis postpolymerization modification reactions, Kiho Matsubara; Li-Chieh Chou; Hideki Amii; Ryohei Kakuchi, 03 Oct. 2022, Molecular Systems Design & Engineering, 7, 10, 1263, 1276, Scientific journal

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• Comparison of functionality and structural stability of bacteriorhodopsin reconstituted in partially fluorinated dimyristoylphosphatidylcholine liposomes with different perfluoroalkyl chain lengths, Mami Hashimoto, Mami; Yuka Murai; Kohei Morita; Takashi Kikukawa; Toshiyuki Takagi; Hiroshi Takahashi; Yasunori Yokoyama; Hideki Amii; Masashi Sonoyama, Oct. 2021, Biochemistry & Molecular Biology; Biophysics, 1863, 10, 183686, 183686, Scientific journal

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• Fundamental insights into aminolysis postpolymerization modification reaction of polymers featuring alpha,alpha-Difluoroacetate Esters, Ryohei Kakuchi; Ryohei; Kota Fukasawa; Li-Chieh Chou; Hyung Kim; Hideki Amii, Sep. 2021, Polymer, 230, 124058, 124058
• Unveiling alpha-Etherification Effects on the Aminolysis of alpha,alpha-Difluoroacetate Enables the Aminolysis Post-polymerization Modification of alpha,alpha-Difluoro-alpha- (aryloxy)acetate-Containing Polymers, Ryohei Kakuchi; Kiho Matsubara; Kota Fukasawa; Hideki Amii, Jun. 2021, 54, 13, 6204, 6213, Scientific journal
• Computer-Aided Design of Postpolymerization Modification Reaction Based on Aminolysis of α,α-Difluoroacetate Esters, Ryohei Kakuchi; Kota Fukasawa; Moriya Kikuchi; Atsushi Narumi; Seigou Kawaguchi; Yao Li; Hyung Kim; Hideki Amii, 12 Jan. 2021, Macromolecules, 54, 1, 364, 372, Scientific journal

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• 3P115 High stability of two-dimensional crystal of reconstituted bacteriorhodopsin in partially fluorinated phosphatidylcholine(03. Membrane proteins,Poster,The 52nd Annual Meeting of the Biophysical Society of Japan(BSJ2014)), Yoshino Masaru; Takahashi Hiroshi; Morita Kohei; Takagi Toshiyuki; Amii Hideki; Kanamori Toshiyuki; Sonoyama Masashi, 2014, Seibutsu Butsuri, 54, 1, S268

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• 1P104 Low affinity of bacteriorhodopsin to partially fluorinated phosphatidylcholine in reconstituted membrane(03.Membrane proteins,Poster,The 51st Annual Meeting of the Biophysical Society of Japan), Yoshino Masaru; Kanayama Kenji; Kikukawa Takashi; Takagi Toshiyuki; Takahashi Hiroshi; Yokoyama Yasunori; Amii Hideki; Kanamori Toshiyuki; Sonoyama Masashi, 2013, Seibutsu Butsuri, 53, 1, S123

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• C-F結合を切る! : 有用フッ素化合物をつくる新プロセス, 網井 秀樹, 01 May 2001, 59, 5, 416, 417

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• Copper-Catalyzed Aromatic Trifluoromethylation via Group Transfer from Fluoral Derivatives, Kondo, Hideaki;Oishi, Masahiro;Fujikawa, Kenichi;Amii, Hideki, 2011, ADVANCED SYNTHESIS & CATALYSIS, 353, 8, 1247, 1252

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• Recent Progress in Catalytic Aromatic Trifluoromethylation, Amii, Hideki, 2011, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 69, 7, 752, 762
• A New Method for Aromatic Difluoromethylation: Copper-Catalyzed Cross-Coupling and Decarboxylation Sequence from Aryl Iodides, Fujikawa, Kenichi;Fujioka, Yasutaka;Kobayashi, Akira;Amii, Hideki, 2011, ORGANIC LETTERS, 13, 20, 5560, 5563

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• Perfluoroalkylation in flow microreactors: generation of perfluoroalkyllithiums in the presence and absence of electrophiles, Nagaki, Aiichiro;Tokuoka, Shinya;Yamada, Shigeyuki;Tomida, Yutaka;Oshiro, Kojun;Amii, Hideki;Yoshida, Jun-ichi, 2011, ORGANIC & BIOMOLECULAR CHEMISTRY, 9, 21, 7559, 7563

  DOI
• Preparation, Structure, and Reactions of Trifluoroacetimidoyl Palladium(II) Complexes, Amii, Hideki;Kageyama, Katsuhiko;Kishikawa, Yosuke;Hosokawa, Tsuyoshi;Morioka, Ryo;Katagiri, Toshimasa;Uneyama, Kenji, 2012, ORGANOMETALLICS, 31, 4, 1281, 1286

  DOI
• An Efficient Route to Difluoromethylated Pyridines, Fujikawa, Kenichi;Kobayashi, Akira;Amii, Hideki, 2012, SYNTHESIS-STUTTGART, 44, 19, 3015, 3018

  DOI
• Effect of Partial Fluorination in the Myristoyl Groups on Thermal and Interfacial Properties of Dimyristoylphosphatidylcholine, Yoshino, Masaru;Takahashi, Hiroshi;Takagi, Toshiyuki;Baba, Teruhiko;Morita, Kohei;Amii, Hideki;Kanamori, Toshiyuki;Sonoyama, Masashi, 2012, CHEMISTRY LETTERS, 41, 11, 1495, 1497

  DOI
• Non-ideal mixing of dimyristoylphosphatidylcholine with its partially fluorinated analogue in hydrated bilayers, Takahashi, Hiroshi;Yoshino, Masaru;Takagi, Toshiyuki;Amii, Hideki;Baba, Teruhiko;Kanamori, Toshiyuki;Sonoyama, Masashi, 2013, CHEMICAL PHYSICS LETTERS, 559, 107, 111

  DOI
• Physicochemical Studies of Bacteriorhodopsin Reconstituted in Partially Fluorinated Phosphatidylcholine Bilayers, Yoshino, Masaru;Kikukawa, Takashi;Takahashi, Hiroshi;Takagi, Toshiyuki;Yokoyama, Yasunori;Amii, Hideki;Baba, Teruhiko;Kanamori, Toshiyuki;Sonoyama, Masashi, 2013, JOURNAL OF PHYSICAL CHEMISTRY B, 117, 18, 5422, 5429

  DOI
• Formation and structure of a fluorinated [2.2]paracyclophan-1-ene, Amii, Hideki;Hayashi, Ryotaro;Seo, Motoharu;Katahira, Yukako;Kobayashi, Akira;Uneyama, Kenji, 2013, JOURNAL OF FLUORINE CHEMISTRY, 152, 90, 93

  DOI
• Flow microreactor synthesis in organo-fluorine chemistry, Amii, Hideki;Nagaki, Aiichiro;Yoshida, Jun-ichi, 2013, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 9, 2793, 2802

  DOI
• Efficient Generation and Increased Reactivity in Cationic Gold via Bronsted Acid or Lewis Acid Assisted Activation of an Imidogold Precatalyst, Han, Junbin;Shimizu, Naoto;Lu, Zhichao;Amii, Hideki;Hammond, Gerald B.;Xu, Bo, 2014, ORGANIC LETTERS, 16, 13, 3500, 3503

  DOI
• Highly Controlled Ring-Opening of Siloxydifluorocyclopropanes: A Versatile Route to Cyclic Fluoroketones, Kageshima, Yoshiya;Suzuki, Chiharu;Oshiro, Kojun;Amii, Hideki, 2015, SYNLETT, 26, 1, 63, 66

  DOI
• Enhancement of stereoselectivities in asymmetric synthesis using fluorinated solvents, auxiliaries, and catalysts, Sugiishi, Tsuyuka;Matsugi, Masato;Hamamoto, Hiromi;Amii, Hideki, 2015, RSC ADVANCES, 5, 22, 17269, 17282

  DOI
• An Origin of Complicated Infrared Spectra of Perfluoroalkyl Compounds Involving a Normal Alkyl Group, Hasegawa, Takeshi;Shimoaka, Takafumi;Tanaka, Yuki;Shioya, Nobutaka;Morita, Kohei;Sonoyama, Masashi;Amii, Hideki;Takagi, Toshiyuki;Kanamori, Toshiyuki, 2015, CHEMISTRY LETTERS, 44, 6, 834, 836

  DOI
• Carbon-carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylations, Sugiishi, Tsuyuka;Amii, Hideki;Aikawa, Kohsuke;Mikami, Koichi, 2015, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 11, 2661, 2670

  DOI
• Surface properties of a single perfluoroalkyl group on water surfaces studied by surface potential measurements, Shimoaka, Takafumi;Tanaka, Yuki;Shioya, Nobutaka;Morita, Kohei;Sonoyama, Masashi;Amii, Hideki;Takagi, Toshiyuki;Kanamori, Toshiyuki;Hasegawa, Takeshi, 2016, JOURNAL OF COLLOID AND INTERFACE SCIENCE, 483, 353, 359

  DOI
• Lateral Diffusion and Molecular Interaction in a Bilayer Membrane Consisting of Partially Fluorinated Phospholipids, Okamoto, Yoshiaki;Motegi, Toshinori;Morita, Kohei;Takagi, Toshiyuki;Amii, Hideki;Kanamori, Toshiyuki;Sonoyama, Masashi;Tero, Ryugo, 2016, LANGMUIR, 32, 41, 10712, 10718

  DOI
• A Convenient Method for Catalytic Aromatic Pentafluoroethylation Using Potassium (Pentafluoroethyl)trimethoxyborate, Sugiishi, Tsuyuka;Kawauchi, Daisuke;Sato, Mizuki;Sakai, Tatsuya;Amii, Hideki, 2017, SYNTHESIS-STUTTGART, 49, 8, 1874, 1878

  DOI
• Trifluoroethoxy-Coated Phthalocyanine Catalyzes Perfluoroalkylation of Alkenes under Visible-Light Irradiation, Matsuzaki, Kohei;Hiromura, Tomoya;Amii, Hideki;Shibata, Norio, 2017, MOLECULES, 22, 7

  DOI
• Predicting Counterion Effects Using a Gold Affinity Index and a Hydrogen Bonding Basicity Index, Lu, Zhichao;Han, Junbin;Okoromoba, Otome E.;Shimizu, Naoto;Amii, Hideki;Tormena, Claudio F.;Hammond, Gerald B.;Xu, Bo, 2017, ORGANIC LETTERS, 19, 21, 5848, 5851

  DOI
• Study of Perfluoroalkyl Chain-Specific Band Shift in Infrared Spectra on the Chain Length, Shimoaka, Takafumi;Sonoyama, Masashi;Amii, Hideki;Takagi, Toshiyuki;Kanamori, Toshiyuki;Hasegawa, Takeshi, 2017, JOURNAL OF PHYSICAL CHEMISTRY A, 121, 44, 8425, 8431

  DOI
• Enolate-Based Strategies to Construct gem-Difluoromethylene Compounds, Amii, Hideki, 2017, JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 75, 11, 1125, 1132
• Nucleophilic fluoroalkylation/cyclization route to fluorinated phthalides, Inaba, Masanori;Sakai, Tatsuya;Shinada, Shun;Sugiishi, Tsuyuka;Nishina, Yuta;Shibata, Norio;Amii, Hideki, 2018, BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 14, 182, 186

  DOI
• Stability of the two-dimensional lattice of bacteriorhodopsin reconstituted in partially fluorinated phosphatidylcholine bilayers, Takahashi, Hiroshi;Yoshino, Masaru;Morita, Kohei;Takagi, Toshiyuki;Yokoyama, Yasunori;Kikukawa, Takashi;Amii, Hideki;Kanamori, Toshiyuki;Sonoyama, Masashi, 2019, BIOCHIMICA ET BIOPHYSICA ACTA-BIOMEMBRANES, 1861, 3, 631, 642

  DOI
• Solvent-Promoted Catalyst-Free Nucleophilic Fluoroalkylation of Aldehydes, Komoda, Kazuki;Shimokawa, Ai;Amii, Hideki, 2019, CHEMISTRYSELECT, 4, 8, 2374, 2378

  DOI
• Raman Optical Activity on a Solid Sample: Identification of Atropisomers of Perfluoroalkyl Chains Having a Helical Conformation and No Chiral Center, Shimoaka, Takafumi;Sonoyama, Masashi;Amii, Hideki;Takagi, Toshiyuki;Kanamori, Toshiyuki;Hasegawa, Takeshi, 2019, JOURNAL OF PHYSICAL CHEMISTRY A, 123, 18, 3985, 3991

  DOI
• Generation and applications of fluorobenzyl anions, Amii, Hideki, 2019, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 257
• Synthesis of 3-fluoro-2,5-disubstituted furans through ring expansion of gem-difluorocyclopropyl ketones, Sugiishi, Tsuyuka;Matsumura, Chihori;Amii, Hideki, 2020, ORGANIC & BIOMOLECULAR CHEMISTRY, 18, 18, 3459, 3462

  DOI
• Computer-Aided Design of Postpolymerization Modification Reaction Based on Aminolysis of alpha,alpha-Difluoroacetate Esters, Kakuchi, Ryohei;Fukasawa, Kota;Kikuchi, Moriya;Narumi, Atsushi;Kawaguchi, Seigou;Li, Yao;Kim, Hyung;Amii, Hideki, 2021, MACROMOLECULES, 54, 1, 364, 372

  DOI
• Unveiling alpha-Etherification Effects on the Aminolysis of alpha,alpha-Difluoroacetate Enables the Aminolysis Post-polymerization Modification of alpha,alpha-Difluoro-alpha-(aryloxy)acetate-Containing Polymers, Kakuchi, Ryohei;Matsubara, Kiho;Fukasawa, Kota;Amii, Hideki, 2021, MACROMOLECULES, 54, 13, 6204, 6213

  DOI
• Fundamental insights into aminolysis postpolymerization modification reaction of polymers featuring alpha,alpha-Difluoroacetate Esters, Kakuchi, Ryohei;Fukasawa, Kota;Chou, Li-Chieh;Kim, Hyung;Amii, Hideki, 2021, POLYMER, 230

  DOI
• Fast-track computational access to reaction mechanisms provides comprehensive insights into aminolysis postpolymerization modification reactions, Matsubara, Kiho;Chou, Li-Chieh;Amii, Hideki;Kakuchi, Ryohei, 2022, MOLECULAR SYSTEMS DESIGN & ENGINEERING, 7, 10, 1263, 1276

  DOI
• Recent Progress in Catalytic Aromatic Trifluoromethylation, Amii Hideki, 2011, Journal of Synthetic Organic Chemistry, Japan, 69, 7, 752, 762
• Effect of Partial Fluorination in the Myristoyl Groups on Thermal and Interfacial Properties of Dimyristoylphosphatidylcholine, YOSHINO Masaru;TAKAHASHI Hiroshi;TAKAGI Toshiyuki;BABA Teruhiko;MORITA Kohei;AMII Hideki;KANAMORI Toshiyuki;SONOYAMA Masashi, Nov. 2012, 41, 11, 1495, 1497
• 22aBW-1 Thermal stability of hexagonal lattice structure of bacteriorhodopsin reconstituted in partially fluorinated phosphatidylcholine Bilayers, Takahashi H.;Yoshino M.;Takagi T.;Kikukawa K.;Amii H.;Kanamori T.;Sonoyama M., 2016, Meeting Abstracts of the Physical Society of Japan, 71.1, 0, 3261
• Effect of Partial Fluorination in the Myristoyl Groups on Thermal and Interfacial Properties of Dimyristoylphosphatidylcholine, Yoshino Masaru;Takahashi Hiroshi;Takagi Toshiyuki;Baba Teruhiko;Morita Kohei;Amii Hideki;Kanamori Toshiyuki;Sonoyama Masashi, 2012, Chemistry Letters, 41, 11, 1495, 1497
• An Origin of Complicated Infrared Spectra of Perfluoroalkyl Compounds Involving a Normal Alkyl Group, Hasegawa Takeshi;Shimoaka Takafumi;Tanaka Yuki;Shioya Nobutaka;Morita Kohei;Sonoyama Masashi;Amii Hideki;Takagi Toshiyuki;Kanamori Toshiyuki, 2015, Chemistry Letters, 44, 6, 834, 836
• 進化し続ける芳香族トリフルオロメチル化法, AMII Hideki, 2014, Farumashia, 50, 1, 19, 23
• Enolate-Based Strategies to Construct gem-Difluoromethylene Compounds, Amii Hideki, 2017, Journal of Synthetic Organic Chemistry, Japan, 75, 11, 1125, 1132
• Fluorous Property of a Short Perfluoroalkyl-Containing Compound Realized by Self-Assembled Monolayer Technique on a Silicon Substrate, Kise Ryuma;Fukumi Aki;Shioya Nobutaka;Shimoaka Takafumi;Sonoyama Masashi;Amii Hideki;Takagi Toshiyuki;Kanamori Toshiyuki;Eda Kazuo;Hasegawa Takeshi, Apr. 2019, Bulletin of the Chemical Society of Japan, 92, 4, 785, 789
• Thermotropic Transition Behaviors of Novel Partially Fluorinated Dimyristoylphosphatidylcholines with Different Perfluoroalkyl Chain Lengths, Morita Kohei;Horikoshi Miki;Yanagi Tamami;Takagi Toshiyuki;Takahashi Hiroshi;Amii Hideki;Hasegawa Takeshi;Sonoyama Masashi, Sep. 2019, Chemistry Letters, 48, 9, 1105, 1108
• Physicochemical studies of bacteriorhodopsin reconstituted in partially fluorinated phosphatidylcholine bilayers., Yoshino Masaru;Kikukawa Takashi;Takahashi Hiroshi;Takagi Toshiyuki;Yokoyama Yasunori;Amii Hideki;Baba Teruhiko;Kanamori Toshiyuki;Sonoyama Masashi, 29 Apr. 2013, The journal of physical chemistry. B, 117, 18

  DOI
• Flow microreactor synthesis in organo-fluorine chemistry., Amii Hideki;Nagaki Aiichiro;Yoshida Jun-Ichi, 05 Dec. 2013, Beilstein journal of organic chemistry, 9

  DOI
• Carbon-carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylations., Sugiishi Tsuyuka;Amii Hideki;Aikawa Kohsuke;Mikami Koichi, 18 Dec. 2015, Beilstein journal of organic chemistry, 11

  DOI
• Surface properties of a single perfluoroalkyl group on water surfaces studied by surface potential measurements., Shimoaka Takafumi;Tanaka Yuki;Shioya Nobutaka;Morita Kohei;Sonoyama Masashi;Amii Hideki;Takagi Toshiyuki;Kanamori Toshiyuki;Hasegawa Takeshi, 22 Aug. 2016, Journal of colloid and interface science, 483

  DOI
• Lateral Diffusion and Molecular Interaction in a Bilayer Membrane Consisting of Partially Fluorinated Phospholipids., Okamoto Yoshiaki;Motegi Toshinori;Morita Kohei;Takagi Toshiyuki;Amii Hideki;Kanamori Toshiyuki;Sonoyama Masashi;Tero Ryugo, 04 Oct. 2016, Langmuir : the ACS journal of surfaces and colloids, 32, 41

  DOI
• Trifluoroethoxy-Coated Phthalocyanine Catalyzes Perfluoroalkylation of Alkenes under Visible-Light Irradiation., Matsuzaki Kohei;Hiromora Tomoya;Amii Hideki;Shibata Norio, 07 Jul. 2017, Molecules (Basel, Switzerland), 22, 7

  DOI
• Study of Perfluoroalkyl Chain-Specific Band Shift in Infrared Spectra on the Chain Length., Shimoaka Takafumi;Sonoyama Masashi;Amii Hideki;Takagi Toshiyuki;Kanamori Toshiyuki;Hasegawa Takeshi, 25 Oct. 2017, The journal of physical chemistry. A, 121, 44

  DOI
• Predicting Counterion Effects Using a Gold Affinity Index and a Hydrogen Bonding Basicity Index., Lu Zhichao;Han Junbin;Okoromoba Otome E;Shimizu Naoto;Amii Hideki;Tormena Cláudio F;Hammond Gerald B;Xu Bo, Organic letters, 19, 21

  DOI
• Nucleophilic fluoroalkylation/cyclization route to fluorinated phthalides., Inaba Masanori;Sakai Tatsuya;Shinada Shun;Sugiishi Tsuyuka;Nishina Yuta;Shibata Norio;Amii Hideki, 19 Jan. 2018, Beilstein journal of organic chemistry, 14

  DOI
• Stability of the two-dimensional lattice of bacteriorhodopsin reconstituted in partially fluorinated phosphatidylcholine bilayers., Takahashi Hiroshi;Yoshino Masaru;Morita Kohei;Takagi Toshiyuki;Yokoyama Yasunori;Kikukawa Takashi;Amii Hideki;Kanamori Toshiyuki;Sonoyama Masashi, 22 Dec. 2018, Biochimica et biophysica acta. Biomembranes, 1861, 3

  DOI
• Raman Optical Activity on a Solid Sample: Identification of Atropisomers of Perfluoroalkyl Chains Having a Helical Conformation and No Chiral Center., Shimoaka Takafumi;Sonoyama Masashi;Amii Hideki;Takagi Toshiyuki;Kanamori Toshiyuki;Hasegawa Takeshi, 27 Mar. 2019, The journal of physical chemistry. A, 123, 18

  DOI
• Comparison of two different partially fluorinated phosphatidylcholines with the perfluorobutyl group on thermotropic properties of the bilayer membrane and reconstituted bacteriorhodopsin., Yanagi Tamami;Takagi Toshiyuki;Takahashi Hiroshi;Kikukawa Takashi;Amii Hideki;Sonoyama Masashi, 22 May 2019, Biophysical reviews, 11, 3

  DOI
• Synthesis of 3-fluoro-2,5-disubstituted furans through ring expansion of gem-difluorocyclopropyl ketones., Sugiishi Tsuyuka;Matsumura Chihori;Amii Hideki, 05 Mar. 2020, Organic & biomolecular chemistry, 18, 18

  DOI
• Thermotropic Transition Behaviors of Novel Partially Fluorinated Dimyristoylphosphatidylcholines with Different Perfluoroalkyl Chain Lengths, Morita, Kohei;Horikoshi, Miki;Yanagi, Tamami;Takagi, Toshiyuki;Takahashi, Hiroshi;Amii, Hideki;Hasegawa, Takeshi;Sonoyama, Masashi, 2019, CHEMISTRY LETTERS, 48, 9, 1105, 1108

  DOI
• Thermodynamic study on hydrated bilayers of ether-linked phosphatidylcholines with terminal perfluorobutyl group, Masaya Miyazaki; Chika Arisaka; Ai Nakagawara; Nanako Sasaki; Hiroshi Takahashi; Toshiyuki Takagi; Hideki Amii; Masashi Sonoyama, Feb. 2024, Biochimica et Biophysica Acta (BBA) - Biomembranes, 1866, 2, 184261, 184261, Scientific journal

  DOI
• Alkylation and silylation of α-fluorobenzyl anion intermediates, Taku Kitahara; Yuta Tagami; Yuto Haga; Santos Fustero; Tsuyuka Sugiishi; Hideki Amii, Nov. 2023, Organic & Biomolecular Chemistry, Scientific journal

  DOI
• Copper‐Catalyzed Aromatic Trifluoromethylation and the Related Transformations, Hideki Amii, 25 Jul. 2023, The Chemical Record, e202300154, Scientific journal

  DOI
• Intramolecular Cyclization of N-Propargylic Amides without Transition-Metal Catalysis for Synthesis of Fluoroalkylated Oxazoles: Using Carboxylic Acid Anhydrides as the Fluoroalkyl Source, Tsuyuka Sugiishi; Ryohei Motegi; Hideki Amii, 04 Jun. 2023, Synthesis, 55, 13, 1984, 1995, Scientific journal

  DOI
• Comparison of functionality and structural stability of bacteriorhodopsin reconstituted in partially fluorinated dimyristoylphosphatidylcholine liposomes with different perfluoroalkyl chain lengths, Hashimoto, Mami;Murai, Yuka;Morita, Kohei;Kikukawa, Takashi;Takagi, Toshiyuki;Takahashi, Hiroshi;Yokoyama, Yasunori;Amii, Hideki;Sonoyama, Masashi, 2021, BIOCHIMICA ET BIOPHYSICA ACTA-BIOMEMBRANES, 1863, 10

  DOI
• Intramolecular Cyclization of N -Propargylic Amides without Transition-Metal Catalysis for Synthesis of Fluoroalkylated Oxazoles: Using Carboxylic Acid Anhydrides as the Fluoroalkyl Source, Sugiishi, Tsuyuka;Motegi, Ryohei;Amii, Hideki, 2023, SYNTHESIS-STUTTGART, 55, 13, 1984, 1995

  DOI
• Copper-Catalyzed Aromatic Trifluoromethylation and the Related Transformations, Amii, Hideki, 2023, CHEMICAL RECORD

  DOI
• Comparison of functionality and structural stability of bacteriorhodopsin reconstituted in partially fluorinated dimyristoylphosphatidylcholine liposomes with different perfluoroalkyl chain lengths., Hashimoto Mami;Murai Yuka;Morita Kohei;Kikukawa Takashi;Takagi Toshiyuki;Takahashi Hiroshi;Yokoyama Yasunori;Amii Hideki;Sonoyama Masashi, Jun. 2021, Biochimica et biophysica acta. Biomembranes, 1863, 10

  DOI
• Copper-Catalyzed Aromatic Trifluoromethylation and the Related Transformations., Amii Hideki, Jul. 2023, Chemical record (New York, N.Y.), 23, 9

  DOI
• Thermodynamic study on hydrated bilayers of ether-linked phosphatidylcholines with terminal perfluorobutyl group., Miyazaki Masaya;Arisaka Chika;Nakagawara Ai;Sasaki Nanako;Takahashi Hiroshi;Takagi Toshiyuki;Amii Hideki;Sonoyama Masashi, Dec. 2023, Biochimica et biophysica acta. Biomembranes, 1866, 2

  DOI

MISC

• 触媒的芳香族トリフルオロメチル化とその関連技術, 網井 秀樹, Aug. 2019, 70, 8, 586, 591
• 進化し続ける芳香族トリフルオロメチル化法, 網井 秀樹, 2014, 50, 1, 19, 23

  DOI
• 急進展する有機フッ素化学, 網井 秀樹, 2014, 67, 1, 45
• Ruppert-Prakash試薬(CF3SiMe3)の新しい使い方, 網井 秀樹, 2014, 1, 1, 4-6.
• 便利！ 汎用試薬を使うトリフルオロメチル化反応, 杉石露佳; 網井秀樹, 2017, 72, 1, 66, 67
• 「芳香族トリフルオロメチル化：触媒反応の新設計」, 網井 秀樹, 2012, 3, 76, 81
• Catalytic asymmetric transformation using fluorinated alcohol, 網井 秀樹, 2011, Fine chemicals, 40, 1, 16, 24
• 芳香族ジフルオロメチル化の進展, 網井 秀樹, Feb. 2020, 月刊ファインケミカル, 49, 2, 39, 48, Introduction scientific journal
• パーフルオロアルキル鎖特有のねじれ構造に起因するアトロプ異性体のラマン分光イメージング法による識別, 下赤卓史; 園山正史; 網井秀樹; 高木俊之; 金森敏幸; 長谷川健, 29 Aug. 2018, 日本分析化学会年会講演要旨集, 67th, 120
• ラマン分光法によるパーフルオロアルキル鎖のねじれ構造解析, 下赤卓史; 園山正史; 網井秀樹; 高木俊之; 金森敏幸; 長谷川健, 06 Mar. 2018, 日本化学会春季年会講演予稿集(CD-ROM), 98th, ROMBUNNO.4E1‐04
• フッ素系自己組織化単分子膜の構造が表面撥水性に与える影響, 黄瀬隆磨; 塩谷暢貴; 下赤卓史; 森田康平; 園山正史; 網井秀樹; 高木俊之; 金森敏幸; 枝和男; 長谷川健, 14 Nov. 2017, フッ素化学討論会講演要旨集, 40th, 40‐41
• 部分フッ素化ジパルミトイルホスファチジルコリンのパーフルオロアルキル鎖長に依存した脂質二分子膜の構造と相転移挙動, 柳瑶美; 茂木俊憲; 高橋浩; 高木俊之; 網井秀樹; 長谷川健; 金森敏幸; 園山正史, 14 Nov. 2017, フッ素化学討論会講演要旨集, 40th, 104‐105
• パーフルオロアルキル鎖長に依存した部分フッ素化リン脂質二分子膜の相転移挙動, 柳瑶美; 堀越未希; 茂木俊憲; 高木俊之; 高橋浩; 網井秀樹; 長谷川健; 金森敏幸; 園山正史, 23 Jun. 2017, 生体分子科学討論会講演要旨集, 44th, 78
• 部分フッ素化ミリスチン酸単分子膜の構造が表面撥水性に与える影響, 黄瀬隆磨; 塩谷暢貴; 下赤卓史; 森田康平; 園山正史; 網井秀樹; 高木俊之; 金森敏幸; 枝和男; 長谷川健, 13 May 2017, 分析化学討論会講演要旨集, 77th, 81
• A Convenient Method for Catalytic Aromatic Pentafluoroethylation Using Potassium (Pentafluoroethyl) trimethoxyborate (vol 49, pg 1874, 2017), Tsuyuka Sugiishi; Daisuke Kawauchi; Mizuki Sato; Tatsuya Sakai; Hideki Amii, Apr. 2017, SYNTHESIS-STUTTGART, 49, 8, E3, E3, Others
• パーフルオロアルキル化合物が示す鎖長に依存するCF伸縮振動バンド特有のシフト, 下赤卓史; 園山正史; 網井秀樹; 高木俊之; 金森敏幸; 長谷川健, 03 Mar. 2017, 日本化学会春季年会講演予稿集(CD-ROM), 97th, ROMBUNNO.2B1‐02
• 部分フッ素化ミリスチン酸単分子膜の分子パッキングが表面撥水性に与える影響, 黄瀬隆磨; 塩谷暢貴; 下赤卓史; 森田康平; 園山正史; 網井秀樹; 高木俊之; 金森敏幸; 枝和男; 長谷川健, 03 Mar. 2017, 日本化学会春季年会講演予稿集(CD-ROM), 97th, ROMBUNNO.3B4‐30
• 新規部分フッ素化ジパルミトイルホスファチジルコリンの熱物性におけるパーフルオロアルキル鎖長依存性, 柳瑶美; 茂木俊憲; 高木俊之; 高橋浩; 網井秀樹; 長谷川健; 金森敏幸; 園山正史, 03 Mar. 2017, 日本化学会春季年会講演予稿集(CD-ROM), 97th, ROMBUNNO.3B4‐38
• 膜タンパク質研究に資する新規部分フッ素化リン脂質ライブラリーの構築:二本鎖脂質の熱物性におけるパーフルオロアルキル鎖長依存性, 柳瑶美; 茂木俊憲; 高木俊之; 高橋浩; 網井秀樹; 長谷川健; 金森敏幸; 園山正史, 29 Sep. 2016, フッ素化学討論会講演要旨集, 39th, 72‐73
• 単一のパーフルオロアルキル基が示す界面物性, 下赤卓史; 田中悠基; 森田康平; 園山正史; 網井秀樹; 高木俊之; 金森敏幸; 長谷川健, 29 Sep. 2016, フッ素化学討論会講演要旨集, 39th, 30‐31
• 新規部分フッ素化リン脂質ライブラリーの構築:膜タンパク質バクテリオロドプシン研究への応用, 吉野賢; 橋本麻美; 堀越未希; 村井裕佳; 森田康平; 柳瑶美; 茂木俊憲; 菊川峰志; 高木俊之; 高橋浩; 網井秀樹; 金森敏幸; 園山正史, 29 Sep. 2016, フッ素化学討論会講演要旨集, 39th, 74‐75
• 部分フッ素化ミリスチン酸の分子凝集に与えるカドミウムイオン添加の影響, 黄瀬隆磨; 下赤卓史; 森田康平; 園山正史; 網井秀樹; 高木俊之; 金森敏幸; 長谷川健, 29 Sep. 2016, フッ素化学討論会講演要旨集, 39th, 84‐85
• パーフルオロアルキル鎖特有の連成振動を考慮したラマンバンドの帰属, 下赤卓史; 泉直毅; 田中悠基; 園山正史; 網井秀樹; 高木俊之; 金森敏幸; 長谷川健, 29 Sep. 2016, フッ素化学討論会講演要旨集, 39th, 86‐87
• 部分フッ素化リン脂質の膜構造の特徴とその膜に再構成したバクテリオロドプシンの二次元格子の熱安定性, 高橋浩; 吉野賢; 高木俊之; 菊川峰志; 網井秀樹; 金森敏幸; 園山正史, Jun. 2016, KEK Proceedings (Web), 2016-2, 388 (WEB ONLY)
• 部分フッ素化リン脂質膜に再構成したバクテリオロドプシンが形成する六方格子構造の熱安定性, 高橋浩; 吉野賢; 高木俊之; 菊川峰志; 網井秀樹; 金森敏幸; 園山正史, 22 Mar. 2016, 日本物理学会講演概要集(CD-ROM), 71, 1, ROMBUNNO.22ABW‐1, 3261

  DOI
• アシル鎖末端をパーフルオロアルキル基で置換した部分フッ素化ジパルミトイルホスファチジルコリンの合成と膜物性の解析, 柳瑶美; 高木俊之; 高橋浩; 網井秀樹; 金森敏幸; 園山正史, 10 Mar. 2016, 日本化学会春季年会講演予稿集(CD-ROM), 96th, ROMBUNNO.4B8‐17
• 部分フッ素化リン脂質を利用した膜タンパク質研究の展開, 園山正史; 吉野賢; 村井裕佳; 森田康平; 菊川峰志; 高木俊之; 高橋浩; 網井秀樹; 金森敏幸, 26 May 2015, 日本蛋白質科学会年会プログラム・要旨集, 15th, 122
• アシル基末端に異なる長さのパーフルオロアルキル基を導入したリン脂質DMPCの膜物性と膜構造, 森田康平; 高橋浩; 網井秀樹; 園山正史; 高木俊之; 金森敏幸, 2015, 物構研サイエンスフェスタ要旨集, 3rd, 85
• 疎水鎖末端をパーフルオロアルキル基に置換したDMPC脂質二分子膜中の膜タンパク質の構造・機能・安定性 2.DMPCを含む二成分系混合膜におけるバクテリオロドプシンの分配挙動, 堀越未希; 吉野賢; 金山賢治; 森田康平; 高橋浩; 網井秀樹; 菊川峰志; 高木俊之; 金森敏幸; 園山正史, 2015, 分子科学討論会講演プログラム&要旨(Web), 9th, ROMBUNNO.3P089 (WEB ONLY)
• 疎水鎖末端をパーフルオロアルキル基に置換したDMPC脂質二分子膜中の膜タンパク質の構造・機能・安定性 1.パーフルオロアルキル基によるバクテリオロドプシンの安定化, 橋本麻美; 村井裕佳; 森田康平; 高橋浩; 網井秀樹; 菊川峰志; 高木俊之; 金森敏幸; 園山正史, 2015, 分子科学討論会講演プログラム&要旨(Web), 9th, ROMBUNNO.3P088 (WEB ONLY)
• リン脂質のアシル鎖の部分フッ素化による再構成バクテリオロドプシンの二次元結晶の安定化, 吉野賢; 高橋浩; 森田康平; 高木俊之; 網井秀樹; 金森敏幸; 園山正史, 26 May 2014, 日本蛋白質科学会年会プログラム・要旨集, 14th, 120
• パーフルオロアルキル鎖長の異なるDMPCアナログ分子の合成と膜物性の解析, 森田康平; 高橋浩; 網井秀樹; 園山正史; 高木俊之; 金森敏幸; 長谷川健, 12 Mar. 2014, 日本化学会講演予稿集, 94th, 3, 766
• パーフルオロアルキル基を導入したDimyristoylphosphatidylcholine二分子膜の物性・構造, 森田康平; 高橋浩; 網井秀樹; 高木俊之; 金森敏幸; 長谷川健; 園山正史, 2014, 分子科学討論会講演プログラム&要旨(Web), 8th, ROMBUNNO.2P074 (WEB ONLY)
• 部分フッ素化リン脂質を含む二成分系リン脂質混合膜における膜タンパク質バクテリオロドプシンの分配挙動, 吉野賢; 金山賢治; 高橋浩; 高木俊之; 菊川峰志; 横山泰範; 網井秀樹; 金森敏之; 園山正史, 07 Jun. 2013, 生体分子科学討論会講演要旨集, 40th, 84, 85
• 部分フッ素化リン脂質・非フッ素化リン脂質二成分混合膜に再構成したバクテリオロドプシンの脂質選択性, 吉野賢; 菊川峰志; 高橋浩; 高木俊之; 網井秀樹; 金森敏幸; 園山正史, 31 May 2013, 日本蛋白質科学会年会プログラム・要旨集, 13th, 59
• 部分フッ素化リン脂質膜中に再構成したバクテリオロドプシンの光サイクルと二次元格子構造について, 高橋浩; 吉野賢; 菊川峰志; 高木俊之; 横山泰範; 網井秀樹; 馬場照彦; 金森敏幸; 園山正史, 2013, 物構研サイエンスフェスタ要旨集, 1st, 57
• ホスファチジルコリン脂質膜の物性・構造に対するアシル鎖へのフッ素原子導入効果, 吉野賢; 高橋浩; 高木俊之; 馬場照彦; 森田康平; 網井秀樹; 金森敏幸; 園山正史, 2012, 分子科学討論会講演プログラム&要旨(Web), 6th, ROMBUNNO.4P055 (WEB ONLY)
• 新規部分フッ素化リン脂質F4‐DMPC二重膜の熱物性と膜の安定性, 上治瑛; 吉野賢; 高橋浩; 高木俊之; 網井秀樹; 馬場照彦; 金森敏幸; 園山正史, 12 Sep. 2011, 日本化学会バイオテクノロジー部会シンポジウム講演要旨集, 14th, 198
• Enviromentally Benign and Safe Synthesis of Organofluorine Compounds, Hideki Amii, Aug. 2021, Chemistry and Chemical Industry, 74, 8, 593, 593, Introduction other
• 部分フッ素化リン脂質F4-DMPC膜に再構成した膜タンパク質バクテリオロドプシンの2次元格子の安定性, 高橋浩; 吉野賢; 森田康平; 高木俊之; 横山泰範; 菊川峰志; 網井秀樹; 金森敏幸; 園山正史; 園山正史; 園山正史, 2019, 2019-7
• 擬環状エーテル型脂質のフッ素化が膜物性および膜タンパク質の構造・機能に及ぼす影響, 川原るい; 高木俊之; 高橋浩; 菊川峰志; 網井秀樹; 園山正史; 園山正史; 園山正史, 2019, 42nd
• パーフルオロアルキル鎖のねじれ構造に起因するアトロプ異性のラマン分光法による識別, 下赤卓史; 園山正史; 網井秀樹; 高木俊之; 金森敏幸; 長谷川健, 2018, 41st
• 部分フッ素化リン脂質二分子膜の熱物性, 森田康平; 柳瑶美; 堀越未希; 高木俊之; 高橋浩; 網井秀樹; 茂木俊憲; 茂木俊憲; 金森敏幸; 長谷川健; 園山正史; 園山正史; 園山正史, 2018, 41st
• 臭化アリールを用いる触媒的芳香族ペルフルオロアルキル化反応, 小茂田和希; 久保田結衣; 杉石露佳; 芹澤宏希; 相川光介; 三上幸一; 網井秀樹, 2016, 96th

Books etc

• Encyclopedia of Reagents for Organic Synthesis, Contributor, Hideki Amii; Yukako Katahira; Akira Kobayashi, Ethyl (hexyl) 2.2-difluoro(trimethylsilyl)ethyl acetate, John Wiley & Sons, 2014, RN01647
• “Fluorine-Containing Synthons”, ACS Symposium Series 911 (Vadim A. Soloshonok Ed.), AMII Hideki, Chap. 27. Mg-Promoted Selective C-F Bond Cleavage: A General and Efficient Access to Difluoroenol Silyl Ethers and Their Derivatives., American Chemical Society
• 「炭素とケイ素の元素科学」（海野雅史編集、松本英之・大谷朝男監修）, Mar. 2014
• 有機フッ素化合物の最新動向 最近のフルオロアルキル化剤の動向., Contributor, 2018
• 「フッ素化：C–F結合の構築」 最新フッ素化学—基礎と応用（第２章）, Contributor, 2010
• 第８章「炭素—フッ素結合の活性化」, Contributor, 2011
• 「第２章 有機フッ素化合物の合成反応」, Contributor, 2015
• Perfluoroalkyl Substances : Synthesis, Applications, Challenges and Regulations, Contributor, Hideki Amii, Chap.3 Perfluoroalkyl Compounds for Industrial and Other Applications Pages 66-112, RSC Publishing, 15 Aug. 2022, ISBN: 9781839165689
• Discover of New Pesticides and Key Intermediates 2022, Contributor, 31 Jan. 2022, ISBN: 9784781316611
• 有機合成のための新触媒反応101, Contributor, Nov. 2021
• Recent Trends in Flow Microreactor Synthesis, Contributor, Hideki Amii, Chap13 Fluorination, Aug. 2021, vii, 254p, ISBN: 9784781316154
• Middle Molecular Strategy-Flow Synthesis to Functional Molecules, Contributor, Hideki Amii, Chap.19 Recent Advances in the Integrated Microflow Synthesis of Organofluorine Compounds, Springer, Jul. 2021
• Technology for Controlled Degradation of Polymeric Materials, Contributor, Apr. 2024, ISBN: 9784781317953
• Innovative Fluorine Chemistry, Contributor, Jan. 2024, ISBN: 9784759814071

Presentations

• Recent Progress in Aromatic Fluoroalkylation, AMII Hideki, International Conference on Chemical Sciences and Nanomaterials (ICCSN2019), 09 Mar. 2019, English, International conference
• Generation and Applications of Fluorobenzyl Anions, AMII Hideki, International Congress on Pure & Applied Chemistry Yangon (ICPAC Yangon 2019), 06 Aug. 2019, English, International conference
• Selective Transformations of Perfluoro Compounds by Flow-Microreactors, AMII Hideki, International Symposium on Fluorous Technologies 2019 (ISoFT19), 10 Aug. 2019, English, International conference
• Recent Progress in Aromatic Difluoromethylation, AMII Hideki, France-Japan Joint Forum on Organofluorine Chemistry for Future Pharmaceutical/Agricultural and Material Sciences, 13 Nov. 2019, English, International conference
• Synthetic Organofluorine Chemistry toward Materials, AMII Hideki, S-Membrane International Conference 2019, 06 Sep. 2019, English, International conference
• 有機フッ素化合物:基礎から最近の合成技術まで, 網井 秀樹, 日本化学会化学技術基礎講座2019 製品開発に必要な有機合成化学の基礎, 01 Oct. 2019, Japanese, Domestic conference
• 急進展する有機フッ素化合物の触媒的合成, 網井 秀樹, 第34回農薬デザイン研究会, 08 Nov. 2019, Japanese, Domestic conference
• Generation and Applications of Fluorobenzyl Anions, AMII Hideki, 257th American Chemical Society (ACS) National Meeting & Exposition, 31 Mar. 2019, English, International conference
• クロスカップリング反応による有機フッ素化合物の合成, 網井 秀樹, 北関東官学 研究会 複合材料懇話会, 07 Dec. 2012
• フッ素化合物合成におけるマイクロフロー・テクノロジー：最近の進展, 網井 秀樹, 近畿化学協会フロー・マイクロ合成研究会・第27回公開講演会, 02 Aug. 2013
• 脱炭酸反応によるジフルオロメチレン化合物の新合成戦略, 網井 秀樹, 名古屋工 業大学ナノライフものづくり研究会, 26 Mar. 2014
• 触媒的芳香族トリフルオロメチル化と関連反応の新開発, 網井 秀樹, 日本化学会関東支部埼玉地区学術講演会,, 28 Nov. 2015
• 有機フッ素化合物の触媒的合成：技術開発と展開, 網井 秀樹, 有機合成化学協会中国四国支部第77回パネル討論会, 19 May 2018, Japanese, Domestic conference
• Recent Progress in Catalytic Aromatic Fluoroalkylation., Hideki Amii, 11th National Meeting on Fluorine Chemistry, Shanghai, Oct. 2010
• New Chiral Phosphine Ligands with Fluoro Alcohol Moieties for Transition Metal-Catalyzed Asymmetric Transformation., Hideki Amii, 第8回日中フッ素化学工業会議ファインケミカル部門, Jun. 2010
• Recent Advances in Cu-Catalyzed Aromatic Trifluoromethylation., Hideki Amii, The 2010 International Chemical Congress of Pacific Basin Societies (Pacifichem), Dec. 2010
• A New Strategy for the Synthesis of Difluoromethylated Aromatics., Hideki Amii, 20th International Symposium on Fluorine Chemistry (ISFC-2012), Jul. 2012
• Recent Advances in Cu-Catalyzed Aromatic Fluoroalkylation., Hideki Amii, Valencia Fluorine Days –Symposium on Fluorine Chemistry–, May 2012
• A Unique Approach to the Synthesis of Difluoromethylated Aromatics., Hideki Amii, 17th Malaysian Chemical Congress (17MCC), Kuala Lumpur, Oct. 2012
• Catalytic Aromatic Trifluoromethylation and Related Reactions, Hideki Amii, 4th International Fluorine Workshop, Apr. 2013
• Generation and Synthetic Applications of Trifluoromethyl Isobenzofurans, Hideki Amii, Vietnam Malaysia International Chemical Congress (VMICC), Nov. 2014
• New Strategies for Aromatic Fluoroalkylation, Hideki Amii, Japan-Russia Joint Seminar on Fluorine Chemistry,, Dec. 2014
• Decarboxylative Route to Difluoromethylene Compounds., Hideki Amii, 21st International Symposium on Fluorine Chemistry & International Symposium on Fluorous Technologies 2015 (21st ISFC_ISoFT), Aug. 2015
• Ingenious Decarboxylative Route to Organofluorine Compounds., Hideki Amii, The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem), Dec. 2015, English
• A Convenient Decarboxylative Route to Difluoromethylene Compounds, Hideki Amii, Symposium on Organic Reactions (ISOR-12), Apr. 2016
• Selective Synthesis of gem-Difluoromethylene Compounds., Hideki Amii, 18th European Symposium on Fluorine Chemistry, Aug. 2016, English, International conference
• Recent Progress in Catalytic Aromatic Trifluoromethylation., Hideki Amii, 3rd International Conference on Past and Present Research Systems of Green Chemistry, Sep. 2016, English, International conference
• Catalytic Aromatic Trifluoromethylation and the Related Reactions., Hideki Amii, Seminar at LHFA, Université Paul Sabatier, Oct. 2016
• Recent Progress in Nucleophilic Fluoroalkylations., Hideki Amii, 14th National Meeting on Fluorine Chemistry, Nov. 2016, English, International conference
• Recent Progress in Catalytic Aromatic Trifluoromethylation., Hideki Amii, International Symposium on Catalysis and Fine Chemicals 2016 (C&FC 2016), Nov. 2016, English, International conference
• Recent Progress in Catalytic Aromatic Fluoroalkylation., Hideki Amii, The 8th International Meeting on Halogen Chemistry (HALCHEM VIII), Sep. 2017
• Recent Progress in Nucleophilic Fluoroalkylations., Hideki Amii, Seminar, Universidad Valencia,, Feb. 2018
• Synthesis and Reactions of Fluorinated Benzocyclobutenone Derivatives., Hideki Amii, 22nd International Symposium on Fluorine Chemistry 2018 (22nd ISFC), Jul. 2018, English, Oxford, UK, International conference
• Synthesis and Reactions of Fluorinated Benzocyclobutenone Derivatives, Hideki Amii, International Congress on Pure & Applied Chemistry Langkawi (ICPAC Langkawi 2018), Nov. 2018, English, International conference
• Generation and Applications of Monofluorobenzyl Anions, Hideki Amii, The 13th International Symposium Symposium on Organic Reactions (ISOR-13), 24 Nov. 2018, Japanese
• Recent Progress of Aromatic Difluoromethylation and the Related Reactions., Hideki Amii, 1st International Symposium of Soft Molecular Activation Research Center (SMARC), Sep. 2018
• 触媒的芳香族トリフルオロメチル化と関連反応の開発., 網井 秀樹, 最新化学談話シリーズ, 九州大学理学部, Dec. 2016
• 急進展する有機フッ素化合物の合成, 網井 秀樹, 第15回有機合成化学談話会（湯河原セミナー）, Sep. 2017
• 触媒的芳香族トリフルオロメチル化反応：最近の進展, 網井 秀樹, 平成23年度触媒学会 ファインケミカルズ合成触媒研究会セミナー「ファインケミカルズの精密合成技術」, May 2011
• フッ素官能基導入クロスカップリング反応の新展開, 網井 秀樹, 平成24年度前期有機合成化学講習会, Jun. 2012
• フッ素官能基導入クロスカップリング反応：最近の進展, 網井 秀樹, 近畿化学協会有機金属部会 平成23年度第4回例会, Jan. 2012
• フッ素官能基導入クロスカップリング反応の新展開, 網井 秀樹, 平成25年度 有機合成夏期セミナー「明日の有機合成化学」, Sep. 2013
• 触媒的芳香族トリフルオロメチル化とその関連反応, 網井 秀樹, 近畿化学協会合成部会・平成25年度第１回合成フォーラム, May 2013
• フッ素系アルコールを活用する不斉触媒反応の創出, 網井 秀樹, フルオラス科学研究会 第６回シンポジウム, Nov. 2013
• 触媒的芳香族トリフルオロメチル化と関連反応, 網井 秀樹, 第26回万有札幌シンポジウム —有機合成化学の挑戦—, Jul. 2014
• 触媒的芳香族トリフルオロメチル化と関連反応, 網井 秀樹, 第30回若手化学者のための化学道場（有機合成化学協会中国四国支部主催, Aug. 2014
• 有機化合物へのフッ素官能基の導入と応用 〜ジフルオロメチレン化合物の合成を中心に〜., 網井 秀樹, 第4回フッ素化学研究講演会, Oct. 2015
• 有機フッ素化合物の触媒的合成の新展開, 網井 秀樹, 第12回触媒相模セミナー, Nov. 2015
• 急進展する有機フッ素化学：基礎から最近の合成技術まで, 網井 秀樹, 平成27年度後期有機合成化学講習会, Nov. 2015
• 触媒的フッ素官能基導入反応の新設計と応用., 網井 秀樹, Ambitious物質科学セミナー, 北海道大学工学部, Sep. 2016
• ジフルオロメチレン化合物合成の新展開, 網井 秀樹, フッ素化学の最前線とフッ素化学工業セミナー 2018, May 2018, Japanese, Domestic conference
• 急進展する有機フッ素化合物の触媒的合成, 網井 秀樹, 第53回有機反応若手の会, 04 Jul. 2018, Japanese, Domestic conference
• Generation and Applications of (Aryl)difluoromethyl Anion Species, Hideki Amii, 26th Winter Fluorine Conference (ACS), Jan. 2023, English
• 有機フッ素化合物：基礎から最近の合成技術まで, 網井 秀樹, 日本化学会化学技術基礎講座2022 製品開発に必要な有機合成化学の基礎, 08 Nov. 2022
• Application of Fluorinated Benzocyclobutenone Derivatives, Hideki Amii, The 15th International Symposium on Organic Reactions (ISOR-15), 05 Nov. 2022, English
• Recent Progress in Application of Fluoroalkyl Isobenzofurans, Hideki Amii, International Congress on Pure & Applied Chemistry Kota Kinabalu (ICPAC KK) 2022, 23 Nov. 2022, English
• トリフルオロメチル化反応の新展開, 網井 秀樹, 第38回有機合成化学セミナー, 29 Sep. 2022
• New Aspects of Nucleophilic Fluoroalkylation, Hideki Amii, 20th European Symposium on Fluorine Chemistry Berlin,Germany, 15 Aug. 2022, English
• Synthetic applications of fluoroalkyl isobenzofurans, Hideki Amii, The 2021 International Chemical Congress of Pacific Basin Societies (Pacifichem 2021), 17 Dec. 2021, 16 Dec. 2021, 21 Dec. 2021, English
• 有機フッ素化合物:基礎から最近の合成技術まで, 網井 秀樹, 日本化学会化学技術基礎講座2021 製品開発に必要な有機合成化学の基礎, 12 Oct. 2021, Japanese
• 新しい含フッ素カルボアニオンの創製と応用, 網井秀樹, 近畿化学協会ヘテロ原子部会 2020年度第2回懇話会, 14 Dec. 2020, Japanese
• Development of Reusable Reagents for Trifluoromethylation, Hideki Amii, The 24 th International Symposium on Fluorine Chemistry, Shanghai, China, 30 Jul. 2024, 28 Jul. 2024, 02 Aug. 2024, English
• Development of Catalytic Aromatic Trifluoromethylation, Hideki Amii, 日本プロセス化学会2024サマーシンポジウム, 05 Jul. 2024, 04 Jul. 2024, 05 Jul. 2024, Japanese
• トリフルオロメチル化イソベンゾフランの発⽣・反応・単離, 網井秀樹, 岡山大学工学部学術講演会, 11 May 2024, Japanese
• 触媒的芳香族トリフルオロメチル化と関連反応の開発, 網井秀樹, 東京大学大学院工学系研究科セミナー, 25 Jan. 2024, 25 Jan. 2024, 25 Jan. 2024, Japanese
• New Aspects of Nucleophilic Fluoroalkylation, Hideki Amii, International Congress on Pure & Applied Chemistry (ICPAC) Bali 2023, 17 Sep. 2023, 12 Sep. 2023, 17 Sep. 2023, English
• 有機フッ素化合物：基礎から最近の合成技術まで, 網井 秀樹, 日本化学会化学技術基礎講座2023 製品開発に必要な有機合成化学の基礎, 11 Sep. 2023, 11 Sep. 2023, 12 Sep. 2023, Japanese
• Isolation and Application of Trifluoromethyl Isobenzofurans, Hideki Amii, 23rd International Symposium on Fluorine Chemistry (23rd ISFC), 27 Jul. 2023, 23 Jul. 2023, 28 Jul. 2023, English
• 芳香族トリフルオロメチル化反応：開発と新展開, 網井秀樹, 徳島大学理工学部特別講演会, 01 Jun. 2023, Japanese
• 芳香族トリフルオロメチル化反応:開発・深化・展開, 網井秀樹, 有機合成化学協会第84回関東支部シンポジウム ー東京農工大シンポジウムー, 13 May 2023, Japanese
• トリフルオロメチル化反応：深化と展開, Hideki Amii, 近畿化学協会ヘテロ原子部会 2022年度第2回懇話会, 06 Dec. 2022, Japanese

Industrial Property Rights

• Patent right, 特願2017-88665, 27 Apr. 2017
• Patent right, 特願2016-154640, 05 Aug. 2016, 特許6751928, 20 Aug. 2020
• Patent right, 特願2009-263316, 18 Nov. 2009
• Patent right, 特願2009-263315, 18 Nov. 2009
• Patent right, 特願2010-003201, 08 Jan. 2010
• Patent right, 特願2011-28545, 14 Feb. 2011
• Patent right, 特願2013-206694, 01 Oct. 2013
• Patent right, 特願2014-034434, 25 Feb. 2014
• Patent right, 特願2017-45744, 10 Mar. 2017, 27 Sep. 2018
• Patent right, 特願2017-063336, 28 Mar. 2017
• Patent right, 特願2017-88665, 27 Apr. 2017, 特許6572484, 23 Aug. 2019

Awards

• The Ichimura Prize for Science for Distinguished Achievement, Hideki Amii, Practical Synthesis of Organofluorine Compounds by Molecular Activation Methodology, Ichimura Foundation for New Technology, Apr. 2019
• Most Outstanding Referees for Angewandte Chemie (Among the top 5% of reviewers for Angewandte Chemie), Wiley, 2018
• 2002
• Award for Poster Contribution, AMII Hideki, The 13th European Symposium on uorine Chemistry, 2001
• 1998
• 1998
• 2010
• 2011
• ACS Publication Awards this Certificate of Recognition (12 Reviews Completed in 2015), 2016
• Most Outstanding Referees for Angewandte Chemie (Among the top 5% of reviewers for Angewandte Chemie), Wiley, 2017
• Certificate of Excellence in Reviewing 2013, Journal of Fluorine Chemistry, 2014
• Certificate of Outstanding Contribution in Reviewing 2013, Tetrahedron, 2013
• Certificate of Outstanding Contribution in Reviewing 2015, Journal of Fluorine Chemistry, 2015
• Outstanding Reviewer Certificate by ChemPubSoc Europe, the Asian Chemical Editorial Society (ACES), and the publisher, Wiley-VCH, 2015
• 2016
• 2017
• 2012
• 2010
• 2015
• 2014
• 2013
• 2015
• 2015
• Symposium Lecture Award, International Congress on Pure & Applied Chemistry (ICPAC), Yangon, Myanmar, Hideki Amii, Aug. 2019
• Symposium Lecture Award, International Congress on Pure & Applied Chemistry (ICPAC), Bali, Indonesia, Hideki Amii, Sep. 2023

Research Projects

• 01 Apr. 2021, 31 Mar. 2025, 21H01927

  対象リソースIRI
• 01 Apr. 2018, 31 Mar. 2020, 18H04381

  対象リソースIRI
• 01 Apr. 2018, 31 Mar. 2020, 18H04235

  対象リソースIRI
• Research of the effects of the hydrogen bonds derived from difluoromethyl group on selective organic reactions, Amii Hideki, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Challenging Exploratory Research, Gunma University, 01 Apr. 2016, 31 Mar. 2019, The present research deals with the effects of the hydrogen bonds derived from difluoromethyl group on selective organic reactions. The difluoromethyl group has been proposed to act as a hydrogen bond donor to a carbonyl oxygen atom. For the effective introduction of a difluoromethyl group into organic molecules, we discovered selective synthesis of o-(difluoromethyl)benzoates by halogen-lithium exchange of (o-bromophenyl)difluoroacetates followed by quenching under basic conditions. Employing EtOH as a quenching agent for the reactions of (o-bromophenyl)difluoroacetates with n-butyllithium in THF at -78 ℃ afforded the corresponding o-(difluoromethyl)benzoates. Furthermore, the intramolecular hydrogen bonding between the difluoromethyl group and the ester moieties in o-(difluoromethyl)benzoates was observed by 1H NMR and IR spectra. Now, we continues the preparation of new organocatalysts possessing difluoromethyl group., 16K13990

  対象リソースIRI
• Synthesis of conjugated organic compounds using fluorinated isobenzofurans, Amii Hideki, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (B), Gunma University, 01 Apr. 2016, 31 Mar. 2019, Fluorinated isobenzofurans are considered to be promising building blocks for the synthesis of fluorine-containing carbocyclic and heterocyclic systems. We have developed a novel method for the generation of trifluoromethylated isobenzofurans. The cascade trifluoromethylation/intramolecular acetalization of o-phthalaldehyde proceeded smoothly to give the lactol in high yield. The lactol easily underwent dehydration under acidic conditions to generate trifluoromethylated isobenzofuran, which underwent the intermolecular Diels-Alder reactions with alkenes to give the adducts in good yields. The resultant bicyclo compounds are good precursors of functionalized 1-trifluoromethylnaphthalenes. For instance, [4+2] cycloaddition with naphthpquinone and the subsequent transformations gave trifluoromethylated tetracene. We have obtained several interesting products by the [4+2] cycloaddition of trifluoromethylated isobenzofuran with 1,4-benzoquinone and acenaphthylene., 16H04143

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• 01 Apr. 2016, 31 Mar. 2018, 16H01129

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• 01 Apr. 2016, 31 Mar. 2018, 16H01003

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• Development of the Transformation of Fluorinated Industrial Wastes, Amii Hideki, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Challenging Exploratory Research, Gunma University, 01 Apr. 2014, 31 Mar. 2017, Fluorine-containing organic molecules play a pivotal role in the remarkable progress of medicinal, agricultural, and material sciences. Nucleophilic introduction of fluoroalkyl groups is one of the most powerful methods for the synthesis of organofluorine compounds. alpha-Fluorobenzyl anions were generated by deprotonation of benzylic fluorides upon treatment with lithium tetramethylpiperidide (LTMP). Nucleophilic reactions using fluorobenzyl anions with electrophiles led to the formation of monofluoroalkyl and difluoroalkyl compounds. Previously, we reported the catalytic procedure for aromatic trifluoromethylation by the use of trifluoroacetaldehyde hemiaminal derivative as a cross-coupling partner in the presence of 10 mol% of CuI and 1,10-phenanthroline (phen). Afrer undertaking a survey of Cu catalysts, we found that for the cross-coupling reactions with aryl iodides, the use of copper thiophene-2-carboxylate (CuTC) as a source of copper(I) affords much improved results., 26550074

  対象リソースIRI
• Decarboxylative Route to Organofluorine Compounds, Amii Hideki, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (B), Gunma University, 01 Apr. 2013, 31 Mar. 2017, Fluorine-containing organic molecules play a pivotal role in the remarkable progress of medicinal, agricultural, and material sciences. Difluoromethylene compounds have been considerable synthetic targets because of their wide utility. Among them, difluoromethylated aromatic compounds (Ar-CF2-R) have received a great deal of attention in the design of bioactive molecules. Previously, we reported the reaction sequence involving cross-coupling and decarboxylation to afford difluoromethyl aromatics (Ar-CF2H). Herein we developed versatile decarboxylative transformations for the synthesis of aromatic compounds bearing functionalized difluoromethyl groups. Upon heating in DMSO or NMP at 170 °C with CuI, potassium 2-aryl-2,2-difluoroacetates underwent decarboxylation to generate aryldifluoromethyl anions (ArCF2-), which reacted with electrophiles to afford a variety of gem-difluoromethylene compounds in moderate to good yields., 25288044

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• 01 Apr. 2013, 31 Mar. 2016, 25105708

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• 01 Apr. 2012, 31 Mar. 2015, 24106706

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• Challenge to Enantioselective C-F Bond Activation, AMII Hideki, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Challenging Exploratory Research, Gunma University, 01 Apr. 2012, 31 Mar. 2015, Organofluorine compounds are widely used as materials such as polymer, liquid crystals, pharmaceutical and agrochemical compounds, and so on. Meanwhile, a new technology for highly selective synthesis of enantiomerically pure organofluorine compounds has been required. Toward stereoselective C-F bond activation, we examined Lewis acid-mediated defluorinative alkylation using gem-difluoromethylene compounds. Organoaluminum compounds were found to promote C-F bond activation of β-fluoro ethanol derivativess. When β, β-difluoro ethanols were treated with a stoichiometric amount of trimethylaluminum, defluorination and the subsequent methylation proceeded smoothly to give the ketones in moderate yields. For the preparation of several gem-difluoromethylene substrates, we developed the cross-coupling routes to 2-aryl-2,2-difluoroacetates. Furthermore, a new strategy for the synthesis of monofluoro compounds involving Mg-promoted defluorination of 2-aryldifluoroacetates have been invented., 24655073

  対象リソースIRI
• New Development of Catalytic Fluoroalkylation, AMII Hideki; HAYASHI Masahiko, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (B), Gunma University, 01 Apr. 2010, 31 Mar. 2013, Organofluorine compounds are the substances of considerable interest in various industrial fields due to their unique physical and chemical properties. Among them, trifluoromethylated aromatic compounds (Ar-CF3) are the substances of considerable interest in various industrial fields. Owing to the increasing demands for fluoroaromatics, new methodologies for aromatic trifluoromethylation have been required from the viewpoints of cost, simplicity, efficiency, versatility, and environmental benignity including a catalytic process. We have succeeded in the development of a catalytic procedure for aromatic trifluoromethylation by the use of trifluoroacetaldehyde hemiaminal derivatives as readily available cross-coupling partners. Furthermore, we have developed reaction sequences leading to efficient synthesis of difluoromethylated aromatics (Ar-CF2H) and monofluoromethylated aromatics (Ar-CFH2) via 2-aryl-2,2-difluoroacetates., 22350043

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• 2010, 2011, 22106531

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• 2008, 2009, 20037050

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• New synthesis of organofluorine compounds using fluorinated carbenes and their derivatives, AMII Hideki; HAYASHI Masahiko, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (B), Kobe University, 2006, 2008, 18350054

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• 2007, 2007, 19028046

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• 2006, 2007, 18655040

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• New Approach for Complete Reversal of Enantioselectivity Using a Single Chiral Source, HAYASHI Masahiko; AMII Hideki, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (B), Kobe University, 2005, 2007, Attempt for obtaining both enantiomers in high enantiomeric excess is attractive and important challenges, because it is often the case that each enantiomer exhibits different bioactivity. This review summarizes some approaches to realize complete reversal of enantioselectivity by changing various conditions. Our new approach to achieve reversal of enantioselection in the reaction of enantioselective addition of diketene to aldehydes affording optically active 5-hydroxy-3-ketoesters in high optical yield using Schiff bases containing oxazoline moiety derived from L-serine, was achieved. Starting from one chiral center (in this case from L-serine), we obtained two chiral Schiff base possessing oxazoline moieties, each of which recognized different enantioface of aldehydes in the addition reaction of diketene to aldehydes in high level (up to 93% ee R and 89% ee (S), respectively). This is the first example of complete reversal of enantioselection from the single chirality of L-serine., 17350020

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• 2004, 2005, 16750081

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• 2004, 2005, 16033241

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• 2003, 2003, 15036249

  対象リソースIRI
• 2002, 2003, 14750684

  対象リソースIRI
• Creation of Fluorinated Amino Acids Library, UNEYAMA Kenji; KATAGIRI Toshimasa; AMII Hideki, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (B), OKAYAMA UNIVERSITY, 2001, 2003, In order to create a library of fluorinated amino acids, a basic study on magnesium-promoted C-F bond activation has been done and then several fluoorinated amino acids have been synthesized stereoselectively. The followings are a summary of the syntheses. 1) Syntheses of optically active β,β-difluoroproline(1) and β,β-difluoroglutamates(2 α-imino-β bromo-β,β-difluoropropanate was enantioselecdvely hydrogenated by Pd(OCOCF3)2 in trifluoroethanol to provide the corresponding amine in 87%ee, which was transformed to (1) and (2) by sequensial chemical reactions. 2) Syntheses of optically active α-trifluoromethyl-α-carboalkoxyaziridine (3) Optically active α-trifluoromethylaziridine was lithiated in THF and carboalkoxylated with chloro formate in 95% yield with retention of the configuration. The aziridine could be ring-opened by the nucleuophiles leading to the general syntheses of α-trifluoromethylated amino acids. 3) Synthese of N, α-C-disilyl-β,β-difluoroenamines (4) and their utilization for fluorinated amino acids Mg-promoted C-F bond activation of trifluoroacetimidoyl chloride in THF provided of N, α-C-bissilyl-β,β-difluoroenamines in excellent yields, which are synthetic equivalents of N, α-C-and α-C-β-C-dianion. The bissilyl enamines could be allcylated stepwise leading to a vaiety of functionalized amino acid precursors. 4) Syntheses of optically active trifluoromethylnorcoronamc acids (5) The intramolecular stereospecific substitution of hydroxy group with cyanide-stabilized carbanion provided optically active trifluoromethylcyclopropanes which could be transformed to amino acids (5). 5) Syntheses of trifluoromethylisocysteine(6) Condensation of trifluoroacetimidoyl chloride with S-protected α-thioacetate followed by disstereoselective reduution of imono moiety and deprotection of thio moiety gave (6). 6) Rhodium catalyzed quinoline ring formation by the reaction of trifluoroacetimidoyl chloride with acetylene carboaylates provided quinoline carboxylates in one-pot reaction., 13555254

  対象リソースIRI
• C-Si bond formation and fluoro(2.2)cylophane synthesis by C-F bond activation, UNEYAMA Kenji; AMII Hideki; KATAGIRI Toshimasa, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (B), OKAYAMA UNIVERSITY, 2000, 2002, Fluorocyclophanes have been recognized as a promising monomer for thermally stable insulator polymer useful for large scale semiconductor manufacturing. In order to develop a practical synthetic method for the cyclophane, Mg-promoted C-F bond activtion has been extensively studied. And one of the protocol for the purpose has been found which consists of reaction of bistrifluoromethyl benzene wirh magnesium in the presence of trimethylsilane in DMF. The reaction provided the desired trimethylsilylated benzyl compound in 50-60% yields. Fluroride-catalyzed desilylated defluorination gave the desired cyclophane via quinodimethane in 53% yield. The present method will be competitive to the Dolbier method based on Zn-metal promoted dechlorinative preparation from the point of availability of bistrifluoromethylbenzene., 12450356

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• 1999, 2000, 11750748

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• 1999, 1999, 11120233

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• SYNTHESIS OF NOVEL FLUORINATED COMPOUNDS BY THE USE OF ACTIVE FLUORINATING REAGENTS, UNEYAMA Kenji; AMII Hideki; KATAGIRI Toshimasa, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (A), OKAYAMA UNIVERSITY, 1997, 1999, 1) C-F bond activation for the creation of difluoromethylene units Selective defluorination from trifluoromethyl group attached to p-system leading to the formation of difluoromethylene and defluorotrimethylsilylmethyl compounds has been developed. In particular, difluoroenolsilyl ethers, difluoroenamines, and 4'-trfluoromethy1, 1-difluorobenzy1 trimethylsilane nave been effectively prepared. The reductive reaction proceeded very smoothy1 by the action of two mole equivalents of metallic magnesium and four mole equivalents of TMS-C1 at 0℃ for 30 min. The industrially feasible production of difluorovinyl monomer for difluorovinyron and octafluoro [2.2 paracyclophane for flurorinated perarylene polymer would be realized. 2) Synthesis of optically active fluorinated amino acids Asymmetric reduction of imino group of 3, 3, 3-trifluoro-2-iminopropanoates was achieved by palladium catalyzed reduction in 3, 3, 3-trifluoroethanol which played an essentially important role for the asymmetric hydrogenation. Syntheses of perfluoroalkylated α-diimines, 2, 2, 3, 3,-tetrafluoro-1, 4-diketones and pinacols. Novel trifluoro- and perfluoroalkyl-α-diimines have been efficiently prepared by the palladium catalyzed coupling reaction of the corresponding imidoyl halides. The diimines could be a promising catalyst for polymerization of alkenes which would be studied in future. Likewise, difluoroenolsilyl ethers and trifluoromethyl ketones have been coupled by Cu (II) oxidation and Zn reduction, respectively., 09305058

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• 1997, 1998, 09750953

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• 1997, 1997, 09239233

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